پیوندهای مفید
اخبار و اعلانات
آمار
| تعداد نشریات | 158 |
| تعداد شماره‌ها | 6,230 |
| تعداد مقالات | 67,766 |
| تعداد مشاهده مقاله | 115,219,224 |
| تعداد دریافت فایل اصل مقاله | 89,965,930 |
کاربرد روش سطح پاسخ جهت بهینه‌سازی حذف رنگزای راکتیو بلک5 با استفاده از آهن (VI) | ||
| نشریه محیط زیست طبیعی | ||
| دوره 76، شماره 2، تیر 1402، صفحه 285-296 اصل مقاله (1 M) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22059/jne.2022.341755.2424 | ||
| نویسندگان | ||
| فاطمه طهرانی1؛ نادر بهرامی فر* 1؛ عباس سیفی2 | ||
| 1گروه علوم و مهندسی محیط زیست دانشکده منابع طبیعی و علوم دریایی، دانشگاه تربیت مدرس، نور، ایران. | ||
| 2رئیس هیئت مدیره و مدیر تحقیق و توسعه صنعت سبز طبرستان، محمودآباد، ایران. | ||
| چکیده | ||
| امروزه توسعة سریع صنایع و بکارگیری صدها ترکیب شیمیایی جدید در آن ها، باعث پیدایش مقادیر عظیمی فاضلاب صنعتی شده که تخلیة آن ها به محیط زیست خصوصاً جریان های آب، آلودگی های شدیدی به‌وجود آورده است. تخلیة پساب های رنگی به اکوسیستم های طبیعی به‌دلیل عملکردهای نامطلوب، خطرات جدی از جمله سرطان زایی، جهش زایی و غیره را برای حیات آبی ایجاد کرده است. در این میان، رنگزای ریاکتیو بلک 5، در سطح جهان کاربرد صنعتی بسیار زیادی به‌خصوص در صنعت نساجی دارد. آهن (VI) به روش الکتروشیمیایی با استفاده از الکترودهای آهن و استیل در محلول پتاسیم هیدروکسید در دمای 65 درجة سانتی گراد سنتز شد و سپس جهت حذف مادة رنگزای ریاکتیو بلک 5 در سیستم حذف ناپیوسته مورد استفاده قرار گرفت. در این مطالعه از روش پاسخ سطح (RSM)، اثر پارامترهای مختلف شامل pH اولیة رنگ، دوز آهن (VI) و زمان و در ادامه از طرح مرکب مرکزی (CCD) برای یافتن بهترین شرایط حذف مورد استفاده قرار گرفت. مقادیر بهینه برای سه متغیر pH، دوز آهن (VI) و زمان به‌ترتیب برابر با 4/5، 24/5میلی گرم و 25 دقیقه به‌دست آمد. در مطالعة حاضر با افزایش دوز آهن (VI) و با گذشت 25 دقیقه از شروع واکنش، بازدهی حذف افزایش یافته، در صورتی که حذف در شرایط اسیدی بهتر از شرایط قلیایی بود. همچنین تحت شرایط بهینه، محلول آهن (VI) توانست 97 درصد از رنگزای ریاکتیو بلک 5 را حذف نماید. در نهایت تحت همین شرایط بر روی پساب واقعی نیز کار شده است و میزان حذف برابر با 95 درصد به‌دست آمد. یافته های این تحقیق نشان داد که آهن (VI) می تواند به‌عنوان یک عامل اکسید‌کنندة مناسب، ارزان قیمت و با کارایی بالا در حذف رنگزای ریاکتیو بلک 5 از پساب صنایع نساجی بکار گرفته شود. | ||
| کلیدواژه‌ها | ||
| آهن (VI)؛ پساب صنایع نساجی؛ روش الکتروشیمیایی؛ روش سطح پاسخ | ||
| عنوان مقاله [English] | ||
| Application of response surface method to optimize the removal of reactive black 5 using Fe (VI) | ||
| نویسندگان [English] | ||
| Fatemeh Tehrani1؛ Nader Bahramifar1؛ Abbas Seifi2 | ||
| 1Department of Environmental Sciences, Faculty of Natural Resources and Marine Science, Tarbiat Modares University, Noor, Iran. | ||
| 2Chairman of the Board and Director of Research and Development of Green Industry Tabarestan, Mahmoudabad, Iran. | ||
| چکیده [English] | ||
| Today, the rapid development of industries and the use of hundreds of new chemical compounds in them have led to the creation of huge amounts of industrial wastewater, the discharge of which into the environment, especially watercourses, has caused severe pollution. The discharge of colored wastewater into natural ecosystems has created serious risks such as carcinogenesis, mutagenicity, etc. for aquatic life due to adverse functions. Meanwhile, Reactive Black 5 has many industrial applications, especially in the textile industry worldwide. Fe (VI) was synthesized electrochemically using iron and steel electrodes in potassium hydroxide solution at 65 ° C and then used to remove the reactive Black 5 in the batch removal system. In this study, the surface response method (RSM), the effect of various parameters including initial color pH, Fe (VI) dose and time and then the central composite design (CCD) were used to find the best removal conditions. The optimal values for the three variables of pH, Fe (VI) dose and time were obtained 4.5, 24.5 mg and 25 minutes, respectively. In the present study, by increasing the Fe (VI) dose and after 25 minutes from the start of the reaction, the removal efficiency increased, if the removal was better in acidic conditions than in alkaline conditions. Also, under the optimal conditions of Fe (VI) solution, it was able to remove 97% of reactive black 5. Finally, under the same conditions, real wastewater was also worked on and the removal rate was 95%. The findings of this study showed that Fe (VI) can be used as a suitable, inexpensive and high-performance oxidizing agent in the removal of reactive Black 5 from textile industry effluents. | ||
| کلیدواژه‌ها [English] | ||
| Fe (VI), Textile industry Wastewater, Electrochemical method, Surface response method | ||
| مراجع | ||
|
Amini, M., Younesi, H., 2009. Biosorption of Cd (II), Ni (II) and Pb (II) from aqueous solution by dried biomass of Aspergillus niger: Application of response surface methodology to the optimization of process parameters. CLEAN–Soil, Air, Water 37(10), 776-786. Audette, R.J., Quail, J.W., Smith, P.J., 1971. Ferrate (VI) ion, a novel oxidizing agent. Tetrahedron Letters 12(3), 279-282. Barışçı, S., Turkay, O., Dimoglo, A., 2016. Review on greywater treatment and dye removal from aqueous solution by ferrate (VI). Ferrites and Ferrates: Chemistry and Applications in Sustainable Energy and Environmental Remediation, pp: 349-409. Bartzatt, R., Nagel, D., 1991. Removal of nitrosamines from waste water by potassium ferrate oxidation. Archives of Environmental Health: An International Journal 46(5), 313-315. Chang, C.Y., Lee, C.L., Pan, T.M., 2006. Statistical optimization of medium components for the production of Antrodia cinnamomea AC0623 in submerged cultures. Applied Microbiology and Biotechnology 72(4), 654-661. Dedushenko, S.K., Perfiliev, Y.D., Goldfeld, M.G., Tsapin, A.I., 2001. Mössbauer study of hexavalent iron compounds. Hyperfine Interactions 136(3), 373-377. Gaya, U.I., Abdullah, A.H., 2008. Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: a review of fundamentals, progress and problems. Journal of Photochemistry and Photobiology C: Photochemistry Reviews 9(1), 1-12. Ghasemi, Z., Younesi, H., Zinatizadeh, A.A., 2016. Preparation, characterization and photocatalytic application of TiO2/Fe-ZSM-5 nanocomposite for the treatment of petroleum refinery wastewater: Optimization of process parameters by response surface methodology. Chemosphere 159, 552-564. Haneef, T., Mustafa, M.R.U., Yasin, H.F., Farooq, S., Isa, M.H., 2020. Study of Ferrate (VI) oxidation for COD removal from wastewater. In IOP Conference Series: Earth and Environmental Science (1), 012007). IOP Publishing. Han, Q., Dong, W., Wang, H., Liu, T., Sun, F., Ying, Y., Yan, X., 2013. Effects of coexisting anions on decolorization of azo dye X-3B by ferrate (VI) and a comparative study between ferrate (VI) and potassium permanganate. Separation and Purification Technology 108, 74-82. Hokkanen, S., Bhatnagar, A., & Sillanpää, M., 2016. A review on modification methods to cellulose-based adsorbents to improve adsorption capacity. Water Research 91, 156-173. Ji, P., Zhang, J., Chen, F., Anpo, M., 2009. Study of adsorption and degradation of acid orange 7 on the surface of CeO2 under visible light irradiation. Applied Catalysis B: Environmental 85(3-4), 148-154. Karri, R.R., Sahu, J.N., 2018. Modeling and optimization by particle swarm embedded neural network for adsorption of zinc (II) by palm kernel shell based activated carbon from aqueous environment. Journal of Environmental Management 206, 178-191. Kang, Y.W., Hwang, K.Y., 2000. Effects of reaction conditions on the oxidation efficiency in the Fenton process. Water Research 34(10), 2786-2790. Kozik, V., Barbusinski, K., Thomas, M., Sroda, A., Jampilek, J., Sochanik, A., Bak, A., 2019. Taguchi method and response surface methodology in the treatment of highly contaminated tannery wastewater using commercial potassium ferrate. Materials 12(22), 3784. Krishanamoorthi, S., Sivakumar, V., Saravanan, K., Prabhu, T.S., 2009. Treatment and reuse of tannery waste water by embedded system. Modern Applied Science 3(1), 129-134. Limmun, W., Ito, A., Ishikawa, N., Momotori, J., Kawamura, Y., Majima, Y., Umita, T., 2019. Removal of nonylphenol and nonylphenol monoethoxylate from water and anaerobically digested sewage sludge by Ferrate (VI). Chemosphere 236, 124399. Li, Y., Li, M., 2011. Treatment of acidic red-dye wastewater by ferrate(VI) oxidation. Journal of Shenyang Jianzhu University (Natural Science) 27(4), 737-740. Lofrano, G., Meric, S., Inglese, M., Nikolau, A., Belgiorno, V., 2010. Fenton oxidation treatment of tannery wastewater and tanning agents: synthetic tannin and nonylphenol ethoxylate based degreasing agent. Desalination and Water Treatment 23(1-3), 173-180. Ma, X., Chen, P., Zhou, M., Zhong, Z., Zhang, F., Xing, W., 2017. Tight ultrafiltration ceramic membrane for separation of dyes and mixed salts (both NaCl/Na2SO4) in textile wastewater treatment. Industrial & Engineering Chemistry Research 56(24), 7070-7079. Moradnia, M., Dindarlo, K., Ali Jamali, H., 2016. Optimizing potassium ferrate for textile wastewater treatment by RSM. Environmental Health Engineering and Management Journal 3(3), 137-142. Rai, P.K., Lee, J., Kailasa, S.K., Kwon, E.E., Tsang, Y.F., Ok, Y.S., Kim, K.H., 2018. A critical review of ferrate (VI)-based remediation of soil and groundwater. Environmental Research 160, 420-448. Rathi, P., Saxena, R.K., Gupta, R., 2001. A novel alkaline lipase from Burkholderia cepacia for detergent formulation. Process Biochemistry 37(2), 187-192. Rodriguez-Rodriguez, J., Ochando-Pulido, J.M., Martinez-Ferez, A., 2019. The Effect of pH in Tannery Wastewater by Fenton vs. Heterogeneous Fenton Process. CET Journal-Chemical Engineering Transactions 73. Roopa, D., Divya, R., & Nathiya, S., 2019. Management of RO reject water from the tannery industry by solar tunnel dryer. International Journal for Advance Research and Development 4(2), 15-20. Samarghandi, M. R., Siboni, M., Maleki, A., Jafari, S.J., Nazemi, F., 2011. Kinetic determination and efficiency of titanium dioxide photocatalytic process in Removal of Reactive Black 5 (RB5) dye and cyanide from aquatic solution. Journal of Mazandaran University of Medical Sciences 21(81), 44-52. Sekaran, G., Chitra, K., Mariappan, M., Raghavan, K.V., 1996. Removal of sulphide in anaerobically treated tannery wastewater by wet air oxidation. Journal of Environmental Science & Health Part A 31(3), 579-598. Song, Z., Williams, C.J., Edyvean, R.G.J., 2004. Treatment of tannery wastewater by chemical coagulation. Desalination 164(3), 249-259. Stanford, C., Jiang, J.Q., Alsheyab, M., 2010. Electrochemical production of ferrate (iron VI): application to the wastewater treatment on a laboratory scale and comparison with iron (III) coagulant. Water, Air, & Soil Pollution 209, 483-488. Talaiekhozani, A., Eskandari, Z., Bagheri, M., & Talaie, M. R., 2016. Removal of H2S and COD using UV, ferrate and UV/ferrate from municipal wastewater. Journal of Human Environment and Health Promotion 2(1), 1-8. Tare, V., Gupta, S., Bose, P., 2003. Case studies on biological treatment of tannery effluents in India. Journal of the Air & Waste Management Association 53(8), 976-982. Thomas, M., Barbusiński, K., Kliś, S., Szpyrka, E., Chyc, M., 2018. Synthetic Textile wastewater treatment using potassium ferrate (VI)–Application of Taguchi method for optimization of experiment. Fibres & Textiles in Eastern Europe 3(129), 104-109. Veisi, F., Veisi, A., 2012. Modeling bisphenol a removal from aqueous solution by activated carbon and eggshell. Journal of Mazandaran University of Medical Sciences 21(2), 129-138. Wang, H. R., Li, G. T., Liu, B. T., Wang, N.G., 2009. Study on Degradation of Wastewater Containing Acid Orange Ⅱ by Ferrate [J]. Journal of North China Institute of Water Conservancy and Hydroelectric Power (Social Sciences Edition) 25(6),102-105. Wang, Q., Luan, Z., Wei, N., Li, J., Liu, C., 2009. The color removal of dye wastewater by magnesium chloride/red mud (MRM) from aqueous solution. Journal of Hazardous Materials 170(2-3), 690-698. Wang, Z. P., Huang, L., Su, J., Xiang, S., Liu, G., Wu, F., 2008. Studies on Treating the Printing and Dyeing Wastewater with the Ferrate Oxidization and Photochemical Process. In 2008 2nd International Conference on Bioinformatics and Biomedical Engineering (pp: 3232-3235). IEEE. Wu, K., Wang, H., Zhou, C., Amina, Y., Si, Y., 2018. Efficient oxidative removal of sulfonamide antibiotics from the wastewater by potassium ferrate. Journal of Advanced Oxidation Technologies 21(1). Xu, G. R., Zhang, Y. P., Li, G. B., 2009. Degradation of azo dye active brilliant red X-3B by composite ferrate solution. Journal of Hazardous Materials 161(2-3), 1299-1305. | ||
|
آمار تعداد مشاهده مقاله: 222 تعداد دریافت فایل اصل مقاله: 116 |
||