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تأثیر بیوچار تفاله پسته بر جذب سطحی فلوراید در محلول آبی | ||
تحقیقات آب و خاک ایران | ||
دوره 52، شماره 3، خرداد 1400، صفحه 825-838 اصل مقاله (1.26 M) | ||
نوع مقاله: مقاله پژوهشی | ||
شناسه دیجیتال (DOI): 10.22059/ijswr.2021.308429.668709 | ||
نویسندگان | ||
ابوالفضل خادمی جلگه نژاد* 1؛ مجید فکری2؛ مجید محمودآبادی3 | ||
1گروه علوم خاک دانشگاه شهید باهنر کرمان ایران | ||
2گروه علوم خاک، دانشگاه شهید باهنر کرمان، کرمان، ایران | ||
3گروه علوم و مهندسی خاک، دانشگاه شهید باهنر کرمان | ||
چکیده | ||
ﻓﻠﻮراﯾﺪ و ﺗﺮﮐﯿﺒﺎت آن ﺑﻪ ﺷﮑﻞ ﮔﺴﺘﺮدهای در ﺻﻨﺎﯾﻊ ﻣﻮرد اﺳﺘﻔﺎده ﻗﺮار ﻣﯽﮔﯿﺮد ﮐﻪ از ﻃﺮﯾﻖ ﭘﺴـﺎب ﺑـﻪ ﻣﺤﯿﻂ زﯾﺴﺖ ﻣﻨﺘﺸﺮ ﻣﯽﺷﻮد. یکی از روشهای حذف فلوراید، جذب سطحی با استفاده از جاذبهای ارزان قیمت است. ﻫﺪف از اﯾﻦ ﺗﺤﻘﯿﻖ ﺑﺮرﺳﯽ ﮐﺎراﯾﯽ اﺳﺘﻔﺎده از بیوچار تفاله پسته در ﺣـﺬف ﻓﻠﻮراﯾـﺪ از ﻣﺤﯿﻂﻫﺎی آﺑﯽ ﻣﯽﺑﺎﺷﺪ. در این پژوهش بیوچار تفاله پسته از طریق گرماکافت در دمای ˚C600 به مدت 3 ساعت با نرخ افزایش دمای 25 درجه سانتیگراد بر دقیقه تهیه شد. به منظور تعیین هم دماهای جذب سطحی،20 میلیلیتر محلول فلوراید با غلظتهای مختلف (صفر،3، 6 و 9 میلیگرم بر لیتر) از نمک NaF به 5/0 گرم بیوچار اضافه شد و سپس نمونهها به مدت 24 ساعت تکان داده شدند و در نهایت مدلهای همدمای لانگمیر، فروندلیچ و تمکین بر دادهای جذب برازش داده شدند. به منظور بررسی اثر زمان بر جذب سطحی فلوراید،20 میلیلیتر محلول فلوراید با غلظتهای اولیه 3، 6 و 9 میلیگرم بر لیتر به 5/0 گرم از بیوچار اضافه شد و نمونهها در فاصله زمانی (15، 30، 45، 60، 90،75، 105، 120، 135، 165، 180، 195، 210 ،225 و 240 دقیقه) تکان داده شدند. سپس غلظت فلوراید اندازهگیری شد. نتایج نشان داد که با افزایش زمان تماس درصد جذب فلوراید به وسیله بیوچار افزایش یافته است و پس از گذشت 240 دقیقه برای غلظتهای 3، 6 و 9 میلیگرم بر لیتر به ترتیب 89/70، 05/63 و 66/54 درصد بدست آمد. مدلهای شبه مرتبه اول و شبه مرتبه دوم نسبت به سایر مدلها، بعنوان بهترین رابطه سینتیک جذب سطحی فلوراید معرفی شدند. نتایج برازش دادههای به دست آمده با مدلهای هم دمای جذب سطحی لانگمیر، فروندلیچ و تمکین نشان داد که مدل لانگمویر توصیف بهتری از فرآیند جذب فلوراید بوسیله بیوچار ارائه مینماید. حداکثر جذب فلوراید ) mg kg-1 (306 توسط بیوچار از مدل لانگمویر بدست آمد. | ||
کلیدواژهها | ||
بیوچار؛ جذب سطحی؛ سینتیک؛ فلوراید؛ همدما | ||
مراجع | ||
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