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Eskandari, S., Tarizade, E., Teymouri, F.. (1395). Sulfunic Acid Modifired MCM-41 Mesoporous Silica as an Efficient Nano-Catalyst for Synthesis of amides and lactams from Oximes Via Beckman Rearrangement. , 27(3), 231-236.
S. Eskandari; E. Tarizade; F. Teymouri. "Sulfunic Acid Modifired MCM-41 Mesoporous Silica as an Efficient Nano-Catalyst for Synthesis of amides and lactams from Oximes Via Beckman Rearrangement". , 27, 3, 1395, 231-236.
Eskandari, S., Tarizade, E., Teymouri, F.. (1395). 'Sulfunic Acid Modifired MCM-41 Mesoporous Silica as an Efficient Nano-Catalyst for Synthesis of amides and lactams from Oximes Via Beckman Rearrangement', , 27(3), pp. 231-236.
Eskandari, S., Tarizade, E., Teymouri, F.. Sulfunic Acid Modifired MCM-41 Mesoporous Silica as an Efficient Nano-Catalyst for Synthesis of amides and lactams from Oximes Via Beckman Rearrangement. , 1395; 27(3): 231-236.

Sulfunic Acid Modifired MCM-41 Mesoporous Silica as an Efficient Nano-Catalyst for Synthesis of amides and lactams from Oximes Via Beckman Rearrangement

Journal of Sciences, Islamic Republic of Iran
مقاله 4، دوره 27، شماره 3، مهر 2016، صفحه 231-236    اصل مقاله (683.77 K)
نوع مقاله: Final File
نویسندگان
S. Eskandari* 1؛ E. Tarizade2؛ F. Teymouri1
11Department of Chemistry, Engineering College, Saveh Branch, Islamic Azad University, Saveh, Islamic Republic of Iran
22Department of Organic Chemistry, Faculty of Basic Sciences, South Tehran Branch, Islamic Azad University, Tehran, Islamic Republic of Iran
چکیده
Mesoporous MCM-41 silicas anchored with sulfonic acid (–SO3H) groups (denoted MSN-SA) via postsynthesis modification are very effective for the Beckman rearrangement. A simple and convenient procedure for conversion of a variety oximes to their corresponding amides and lactams has been developed. The reaction was carried out in the presence of MSN-SA as the catalyst. The best results for conversion of oximes to amides and lactams were obtained in the presence of MSN-SA and solvent free condition at 110 ºC. Excellent yields were obtained from oximes with electron-donating and electron-withdrawing groups. The system also worked well with polynuclear aromatic, heterocyclic and aliphatic oximes. 
کلیدواژه‌ها
Oxime, MCM-4؛ Sulfonic acid؛ Beckman rearrangement
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