From The Rational Design of Cobalt-zinc Bimetallic MOF to Catalytic Behavior in Knoevenagel Condensation Reaction | ||
| Journal of Sciences, Islamic Republic of Iran | ||
| مقاله 2، دوره 35، شماره 1، بهار 2024، صفحه 15-23 اصل مقاله (1.02 M) | ||
| نوع مقاله: Original Research Articles | ||
| شناسه دیجیتال (DOI): 10.22059/jsciences.2024.376401.1007864 | ||
| نویسندگان | ||
| Alireza Abbasi* 1؛ Saeideh Tavakkoli2؛ Mahdiyeh-Sadat Hosseini3 | ||
| 11 School of Chemistry, College of Science, University of Tehran, Tehran, Islamic Republic of Iran | ||
| 22 Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Islamic Republic of Iran | ||
| 33 School of Chemistry, College of Science, University of Tehran, Tehran, Islamic Republic of Iran | ||
| چکیده | ||
| In this study, a bimetallic Co-Zn metal-organic framework (Co-Zn-MOF) was synthesized through solvothermal conditions by using Co2+ and Zn2+ salts, DABCO and H2BDC as the rigid ligands (DABCO= 1,4-diazabicyclo (2.2.2) octane, H2BDC=Benzene-1,4-dicarboxylic acid). This bimetallic MOF was used as a catalyst for the Knoevenagel condensation reaction and exhibited enhanced catalytic activity compared to its parents' single metal MOFs derived from DABCO and H2BDC precursors (Co-MOF and Zn-MOF) at mild reaction conditions, which could be attributed to the synergistic effect between the metal ions. | ||
| کلیدواژهها | ||
| Metal-organic framework؛ Bimetal-MOF؛ Heterogeneous catalyst؛ Knoevenagel | ||
| مراجع | ||
|
| ||
|
آمار تعداد مشاهده مقاله: 723 تعداد دریافت فایل اصل مقاله: 808 |
||