Kinetics Study of Oxidative Desulfurization of Real Diesel Fuel Over Uncoated and Coated Nano-catalysts in an Oscillatory Helical Baffled Reactor

[1] Mjalli FS, Ahmed OU, Al-Wahaibi T, Al-Wahaibi Y, AlNashef IM. Deep oxidative desulfurization of liquid fuels. Reviews in Chemical Engineering. 2014 Aug 1;30(4):337-78. https://doi.org/10.1515/revce-2014-0001

[2] Nawaf AT, Gheni SA, Jarullah AT, Mujtaba IM. Improvement of fuel quality by oxidative desulfurization: Design of synthetic catalyst for the process. Fuel Processing Technology. 2015 Oct 1;138:337-43. https://doi.org/10.1016/j.fuproc.2015.05.033

[3] El-Gendy NS, Speight JG. Handbook of refinery desulfurization. CRC Press; 2015 Sep 18.

[4] Shafiq I, Shafique S, Akhter P, Yang W, Hussain M. Recent developments in alumina supported hydrodesulfurization catalysts for the production of sulfur-free refinery products: A technical review. Catalysis Reviews. 2022 Jan 2;64(1):1-86. https://doi.org/10.1080/01614940.2020.1780824

[5] Speight JG. The desulfurization of heavy oils and residua. CRC Press; 1999 Nov 5.

[6] Srivastava VC. An evaluation of desulfurization technologies for sulfur removal from liquid fuels. Rsc Advances. 2012;2(3):759-83. https://doi.org/10.1039/C1RA00309G

[7] Dhir S, Uppaluri R, Purkait MK. Oxidative desulfurization: Kinetic modelling. Journal of hazardous materials. 2009 Jan 30;161(2-3):1360-8. https://doi.org/10.1016/j.jhazmat.2008.04.099

[8] Houda S, Lancelot C, Blanchard P, Poinel L, Lamonier C. Oxidative desulfurization of heavy oils with high sulfur content: A review. Catalysts. 2018 Aug 23;8(9):344. https://doi.org/10.3390/catal8090344

[9] Marafi A, Albazzaz H, Rana MS. Hydroprocessing of heavy residual oil: Opportunities and challenges. Catalysis today. 2019 Jun 1;329:125-34. https://doi.org/10.1016/j.cattod.2018.10.067

[10] Julião D, Valença R, Ribeiro JC, de Castro B, Balula SS. Efficient eco-sustainable ionic liquid-polyoxometalate desulfurization processes for model and real diesel. Applied Catalysis A: General. 2017 May 5;537:93-9. https://doi.org/10.1016/j.apcata.2017.02.021

[11] Li J, Yang Z, Li S, Jin Q, Zhao J. Review on oxidative desulfurization of fuel by supported heteropolyacid catalysts. Journal of Industrial and Engineering Chemistry. 2020 Feb 25;82:1-6. https://doi.org/10.1016/j.jiec.2019.10.020 

[12] Mahmood QA, Abdulmajeed BA, Haldhar R. Oxidative Desulfurization of Simulated Diesel Fuel by Synthesized Tin Oxide Nano-Catalysts Support on Reduced Graphene Oxide. Iraqi Journal of Chemical and Petroleum Engineering. 2023 Dec 30;24(4):83-90. https://doi.org/10.31699/IJCPE.2023.4.8

[13] Liu H, Min E. Catalytic oxidation of mercaptans by bifunctional catalysts composed of cobalt phthalocyanine supported on Mg–Al hydrotalcite-derived solid bases: effects of basicity. Green Chemistry. 2006;8(7):657-62. https://doi.org/10.1039/B603461F

[14] Fathi MI, Humadi JI, Mahmood QA, Nawaf AT, Ayoub RS RS. Improvement of design synthetic nano-catalysts for performance enhancement of oxidative desulfurization using batch reactor. InAIP Conference Proceedings 2022 Nov 17 (Vol. 2660, No. 1). AIP Publishing. https://doi.org/10.1063/5.0109089

[15] Rezvani MA, Aghmasheh M. Synthesis of t‐B. PWFe/NiO nanocomposite as an efficient and heterogeneous green nanocatalyst for catalytic oxidative‐extractive desulfurization of gasoline. Environmental Progress & Sustainable Energy. 2021 Jul;40(4):e13616. https://doi.org/10.1002/ep.13616

[16] Abdulateef LT, Nawaf AT, Mahmood QA, Dahham OS, Noriman NZ, Shayfull Z. Preparation, characterization and application of alumina nanoparticles with multiple active component for oxidation desulfurization. InAIP Conference Proceedings 2018 Nov 9 (Vol. 2030, No. 1). AIP Publishing. https://doi.org/10.1063/1.5066672

[17] Rezvani MA, Shaterian M, Aghbolagh ZS, Akbarzadeh F. Synthesis and characterization of new inorganic‐organic hybrid nanocomposite PMo11Cu@ MgCu2O4@ CS as an efficient heterogeneous nanocatalyst for ODS of real fuel. ChemistrySelect. 2019 May 31;4(20):6370-6. https://doi.org/10.1002/slct.201900202

[18] Abdulateef LT, Nawaf AT, Al-Janabi OY, Foot PJ, Mahmood QA. Batch oxidative desulfurization of model light gasoil over a bimetallic nanocatalyst. Chemical Engineering & Technology. 2021 Sep;44(9):1708-15. https://doi.org/10.1002/ceat.202100027

[19] Cao X, Tong R, Wang J, Zhang L, Wang Y, Lou Y, Wang X. Synthesis of Flower-Like Cobalt–Molybdenum Mixed-Oxide Microspheres for Deep Aerobic Oxidative Desulfurization of Fuel. Molecules. 2023 Jun 28;28(13):5073. https://doi.org/10.3390/molecules28135073

[20] Nawaf AT, Jarullah AT, Abdulateef LT. Design of a synthetic zinc oxide catalyst over nano-alumina for sulfur removal by air in a batch reactor. Bulletin of Chemical Reaction Engineering & Catalysis. 2019;14(1):79. https://doi.org/10.9767/bcrec.14.1.2507.79-92

[21] Nawaf AT, Jarullah AT, Gheni SA, Mujtaba IM. Development of kinetic and process models for the oxidative desulfurization of light fuel, using experiments and the parameter estimation technique. Industrial & Engineering Chemistry Research. 2015 Dec 23;54(50):12503-15. https://doi.org/10.1021/acs.iecr.5b03289

[22] Shiraishi Y, Hirai T. Desulfurization of vacuum gas oil based on chemical oxidation followed by liquid− liquid extraction. Energy & Fuels. 2004 Jan 21;18(1):37-40. https://doi.org/10.1021/ef0301396

[23] Humadi JI, Nawaf AT, Jarullah AT, Ahmed MA, Hameed SA, Mujtaba IM. Design of new nano-catalysts and digital basket reactor for oxidative desulfurization of fuel: Experiments and modelling. Chemical Engineering Research and Design. 2023 Feb 1;190:634-50. https://doi.org/10.1016/j.cherd.2022.12.043

[24] Mahmood Q. Performance of tin oxide supported on reduced graphene oxide for oxidative desulfurization. El-Cezeri. 2023 May 5;10(2):284-95. https://doi.org/10.31202/ecjse.1210453

[25] Hameed SA, Nawaf AT, Mahmood QA, Abdulateef LT, Jarullah AT, Mujtaba IM. Production of Green Fuel: A Digital Baffle Batch Reactor for Enhanced Oxidative Desulfurization of Light Gas Oil Using Nano-Catalyst. Iran. J. Chem. Chem. Eng. Research Article Vol. 2023;42(3). https://doi.org/10.30492/ijcce.2022.547416.5138

[26] Humadi JI, Gheni SA, Ahmed SM, Abdullah GH, Phan AN, Harvey AP. Fast, non-extractive, and ultradeep desulfurization of diesel in an oscillatory baffled reactor. Process Safety and Environmental Protection. 2021 Aug 1;152:178-87. https://doi.org/10.1016/j.psep.2021.05.028

[27] Nawaf AT, Abdulmajeed BA. Design of oscillatory helical baffled reactor and dual functional mesoporous catalyst for oxidative desulfurization of real diesel fuel. Chemical Engineering Research and Design. 2024 Sep 1;209:193-209. https://doi.org/10.1016/j.cherd.2024.07.032

[28] Nawaf AT, Gheni SA, Jarullah AT, Mujtaba IM. Optimal design of a trickle bed reactor for light fuel oxidative desulfurization based on experiments and modeling. Energy & Fuels. 2015 May 21;29(5):3366-76. https://doi.org/10.1021/acs.energyfuels.5b00157

[29] Ahmed SM, Phan AN, Harvey AP. Mass transfer enhancement as a function of oscillatory baffled reactor design. Chemical Engineering and Processing-Process Intensification. 2018 Aug 1;130:229-39. https://doi.org/10.1016/j.cep.2018.06.016

[30] Jafar SA, Nawaf AT, Humadi JI. Improving the extraction of sulfur-containing compounds from fuel using surfactant material in a digital baffle reactor. Materials Today: Proceedings. 2021 Jan 1;42:1777-83. https://doi.org/10.1016/j.matpr.2020.11.821

[31] Mohammed ST, Gheni SA, Aqar DY, Hamad KI, Ahmed SM, Mahmood MA, Abdullah GH, Ali MK. Evaluation and optimal design of a high stability hydrothermal deoxygenation process for production of green diesel fuel via deoxygenation of waste cooking oil. Process Safety and Environmental Protection. 2022 Mar 1;159:489-99. https://doi.org/10.1016/j.psep.2022.01.006

[32] Nawaf AT, Hamed HH, Hameed SA, Jarullah AT, Abdulateef LT, Mujtaba IM. Performance enhancement of adsorption desulfurization process via different new nano-catalysts using digital baffle batch reactor and mathematical modeling. Chemical Engineering Science. 2021 Mar 15;232:116384. https://doi.org/10.1016/j.ces.2020.116384

[33] Nawaf AT, Hameed SA, Abdulateef LT, Jarullah AT, Kadhim MS, Mujtaba IM. A novel synthetic nano-catalyst (Ag2O3/Zeolite) for high quality of light naphtha by batch oxidative desulfurization reactor. https://doi.org/10.9767/bcrec.16.4.11383.716-732

[34] Nawaf AT, Humadi JI, Jarullah AT, Ahmed MA, Hameed SA, Mujtaba IM. Design of nano-catalyst for removal of phenolic compounds from wastewater by oxidation using modified digital basket baffle batch reactor: experiments and modeling. Processes. 2023 Jul 1;11(7):1990. https://doi.org/10.3390/pr11071990

[35] Al-Dahhan M. Recent advances and scale-up of trickle bed reactors for energy and environmental applications. InProceedings of the International Symposium on Advances in Hydroprocessing of Oil Fractions (ISAHOF 2007) 2007 Jun 26 (pp. 26-29).

[36] Sachdeva TO, Pant KK. Deep desulfurization of diesel via peroxide oxidation using phosphotungstic acid as phase transfer catalyst. Fuel processing technology. 2010 Sep 1;91(9):1133-8. https://doi.org/10.1016/j.fuproc.2010.03.027

[37] Rezvani MA, Aghmasheh M. Synthesis and characterization of new nanocomposite TBA-PW11Ni@ NiO as an efficient and reusable heterogeneous catalyst in oxidative desulphurization of gasoline. Journal of the Taiwan Institute of chemical engineers. 2017 Aug 1;77:321-8. https://doi.org/10.1016/j.jtice.2017.05.014

[38] Shi Y, Fan M. Reaction kinetics for the catalytic oxidation of sulfur dioxide with microscale and nanoscale iron oxides. Industrial & engineering chemistry research. 2007 Jan 3;46(1):80-6. https://doi.org/10.1021/ie060889d