Removal of Benzyl butyl phthalate by Polyetheretherketone/polyvinylalcohol nanocomposite Modified with Zinc oxide nanoparticles Adsorbent from Wastewater | ||
| Pollution | ||
| مقاله 15، دوره 10، شماره 2، تابستان 2024، صفحه 833-846 اصل مقاله (719.02 K) | ||
| نوع مقاله: Original Research Paper | ||
| شناسه دیجیتال (DOI): 10.22059/poll.2024.371983.2242 | ||
| نویسندگان | ||
| Reza Cheraghi1؛ Maryam Abrishamkar* 2؛ Hossein Jalali Jahromi1؛ Farzaneh Hoseini1 | ||
| 1Department of Chemistry, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran | ||
| 2Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran | ||
| چکیده | ||
| The applicability of Polyetheretherketone/polyvinylalcohol nanocomposite modified with zinc oxide nanoparticles synthesis for the removal of benzyl butyl phthalate from wastewater. Identical techniques, including BET, FT-IR, XRD, and SEM, have to characterize this unknown material. The investigation shows the applicability of adsorbent PEEK/PVA/ZnONPs, as an available, suitable, and low-cost adsorbent for adequately removing the benzyl butyl phthalate from wastewater. The impacts of variables, including benzyl butyl phthalate concentration, adsorbent, pH, and time (15 mgL-1, 0.3 g, 5.0, and 60 min). Based on the received data, the adsorption of benzyl butyl phthalate on the PEEK/PVA/ZnONPs adsorbent agrees well with the Langmuir adsorption model isotherm (qm = 34.24 mgg-1). The results of the thermodynamic parameter showed a negative enthalpy (-77.0 KJ/mol), a negative Gibbs free energy (-11.7 KJ/mol), and negative entropy (-274.0 J/K.mol). This led to the conclusion that the adsorption process is energetically possible, and exothermic was also spontaneous. This work indicates that the PEEK/PVA/ZnONPs, used as an ecologically adapted, adsorbent holds promise for eliminating benzyl butyl phthalate from wastewater. | ||
| کلیدواژهها | ||
| Benzyl butyl phthalate؛ Adsorption؛ Composite Membrane؛ Zinc Oxide Nanoparticles؛ Wastewater | ||
| مراجع | ||
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