Modeling and Optimization: Isomerization Reaction Rate using Response Surface Methodology with Two Kinetic Model Over Bi-Porous Catalysts

[1] Parsafard N, Peyrovi MH, Rashidzadeh M. n-Heptane isomerization on a new kind of
micro/mesoporous catalyst: Pt supported on HZSM-5/HMS. Microporous. Mesoporous.
Mater. 2014 Dec 1; 200:190-8. https://doi.org/10.1016/j.micromeso.2014.08.044
[2] Teh LP, Setiabudi HD, Sidik SM, Annuar NH, Jalil AA. Synergic role of platinum (Pt) and
molybdenum trioxide (MoO3) promoted HBEA zeolite towards n-heptane isomerization.
Mater. Chem. Phys. 2021 Apr 15; 263:124406.
https://doi.org/10.1016/j.matchemphys.2021.124406
[3] Peyrovi MH, Parsafard N, Peyrovi P. Influence of zirconium addition in platinum–
hexagonal mesoporous silica (Pt-HMS) catalysts for reforming of n-heptane. Ind. Eng.
Chem. Res. 2014 Sep 17; 53(37):14253-62. https://doi.org/10.1021/ie5024244
[4] Zhang B, Zhou W, Zhang J, Gao Z, Cheng D, Tang L, Liu X, Song Y, Dong C, Xu Y, Yan
J. Adjacent Pt nanoparticles and sub-nanometer WOx clusters determine catalytic
isomerization of C7H16. CCS Chem. 2021 Nov 30:3371-82. 

https://doi.org/10.31635/ccschem.021.202101454 

[5] Ghaderi Z, Peyrovi MH, Parsafard N. n-Heptane isomerization activities of Pt catalyst
supported on micro/mesoporous composites. BMC Chem. 2021 Dec; 15(1):1-8.
https://doi.org/10.1186/s13065-021-00787-6
[6] Parsafard N, Peyrovi MH, Jarayedi M. Catalytic study and kinetic modeling of the nheptane isomerization over Pt/Al-HMS/HZSM-5 hybrid catalysts. Energy Fuel. 2017 Jun
15; 31(6):6389-96. https://doi.org/10.1021/acs.energyfuels.7b00657
[7] De Luna MD, Sablas MM, Hung CM, Chen CW, Garcia-Segura S, Dong CD. Modeling
and optimization of imidacloprid degradation by catalytic percarbonate oxidation using
artificial neural network and Box-Behnken experimental design. Chemosphere. 2020 Jul 1;
251:126254. https://doi.org/10.1016/j.chemosphere.2020.126254
[8] Jiang N, Zhao Y, Qiu C, Shang K, Lu N, Li J, Wu Y, Zhang Y. Enhanced catalytic
performance of CoOx-CeO2 for synergetic degradation of toluene in multistage sliding
plasma system through response surface methodology (RSM). Appl. Catal. B: Env. 2019
Dec 15; 259:118061. https://doi.org/10.1016/j.apcatb.2019.118061
[9] Ong MY, Nomanbhay S, Kusumo F, Raja Shahruzzaman RM, Shamsuddin AH. Modeling
and optimization of microwave-based bio-jet fuel from coconut oil: Investigation of
response surface methodology (RSM) and artificial neural network methodology (ANN).
Energies. 2021 Jan 7; 14(2):295. https://doi.org/10.3390/en14020295
[10] Hasanudin H, Asri WR, Said M, Hidayati PT, Purwaningrum W, Novia N, Wijaya K.
Hydrocracking optimization of palm oil to bio-gasoline and bio-aviation fuels using
molybdenum nitride-bentonite catalyst. RSC Adv. 2022 Jun 1; 12(26):16431-16443.
https://doi.org/10.1039/D2RA02438A
[11] Gupta P, Nayak KK. Optimization of keratin/alginate scaffold using RSM and its
characterization for tissue engineering. Inter. J. Biol. Macromol. 2016 Apr 1; 85:141-9.
https://doi.org/10.1016/j.ijbiomac.2015.12.010
[12] Silva AF, Neves P, Rocha SM, Silva CM, Valente AA. Optimization of continuous-flow
heterogeneous catalytic oligomerization of 1-butene by design of experiments and response
surface methodology. Fuel. 2020 Jan 1; 259:116256.
https://doi.org/10.1016/j.fuel.2019.116256
[13] Parsafard N, Garmroodi A, Mirzaei S. Gas‐phase catalytic isomerization of n‐heptane using
Pt/(CrOx/ZrO2)‐HMS catalysts: A kinetic modeling. Int. J. Chem. Kinet. 2021 Aug;
53(8):971-81. https://doi.org/10.1002/kin.21497
[14] Hamied RS, Shakor ZM, Sadeiq AH, Razak AAA, Khadim AT. Kinetic modeling of light
naphtha hydroisomerization in an industrial universal oil products Penex™ unit. Energy
Eng. 2023 Feb 13; 120:1371-1386. https://doi.org/10.32604/ee.2023.028441
[15] Fatah NAA, Triwahyono S, Jalil AA, Salamun N, Mamat CR, Majid ZA. n-Heptane
isomerization over molybdenum supported on bicontinuous concentric lamellar silica KCC1: Influence of phosphorus and optimization using response surface methodology (RSM).
Chem. Eng. J. 2017 April 15; 314:650-659. https://doi.org/10.1016/j.cej.2016.12.028
[16] Elfghi FM, Amin NAS, Elgarni MM. Optimization of isomerization activity and
aromatization activity in catalytic naphtha reforming over tri-metallic modified catalyst
using design of experiment based on central composite design and response surface
methodology. J. Adv. Catal. Sci. Technol. 2015 March 4; 2(1):1-17.
http://dx.doi.org/10.15379/2408-9834.2015.02.01.1
[17] Nasri Z, Mozafari M. Multivariable statistical analysis and optimization of Iranian heavy
crude oil upgrading using microwave technology by response surface methodology (RSM).
J. Petrol. Sci. Eng. 2018 Feb; 161:427-444. https://doi.org/10.1016/j.petrol.2017.12.004