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Mamedov, Ibrahim, Azimova, Nargiz, Javadova, Ofeliya. (1402). Testing of Glycerol Ketals as Components of B20, B50 Fuel Blends. , 57(1), 27-35. doi: 10.22059/jchpe.2023.313163.1336
Ibrahim Mamedov; Nargiz Azimova; Ofeliya Javadova. "Testing of Glycerol Ketals as Components of B20, B50 Fuel Blends". , 57, 1, 1402, 27-35. doi: 10.22059/jchpe.2023.313163.1336
Mamedov, Ibrahim, Azimova, Nargiz, Javadova, Ofeliya. (1402). 'Testing of Glycerol Ketals as Components of B20, B50 Fuel Blends', , 57(1), pp. 27-35. doi: 10.22059/jchpe.2023.313163.1336
Mamedov, Ibrahim, Azimova, Nargiz, Javadova, Ofeliya. Testing of Glycerol Ketals as Components of B20, B50 Fuel Blends. , 1402; 57(1): 27-35. doi: 10.22059/jchpe.2023.313163.1336

Testing of Glycerol Ketals as Components of B20, B50 Fuel Blends

Journal of Chemical and Petroleum Engineering
دوره 57، شماره 1، شهریور 2023، صفحه 27-35    اصل مقاله (305.92 K)
نوع مقاله: Research Paper
شناسه دیجیتال (DOI): 10.22059/jchpe.2023.313163.1336
نویسندگان
Ibrahim Mamedov* ؛ Nargiz Azimova؛ Ofeliya Javadova
department of chemistry, Baku State University, Azerbaijan
چکیده
The aim of the present work was to the synthesis of glycerol ketals by using p-toluenesulfonic acid (PTSA), their applications in biodiesel blends. Biodiesel was prepared from the sunflower oil by the transesterification reaction in the presence of a new catalytic system. The conversion was 83% at using a 1:3 molar ratio of oil to alcohol at 55°C. The use of the proposed catalytic system reduces the amount of foam produced by biodiesel washing, thus simplifying its synthesis. Due to the absence of the neutralization stage, the described catalytic system can be reused after water removal through distillation. Important fuel physical properties of diesel, biodiesel, and oxygenated diesel blends with the ASTM standards had been investigated. Based on the obtained results is noted that the fuel blends B20 and B50 with (or without) the oxygenated have greater potentials for diesel engines than, B100 and diesel. The structures of the obtained products were investigated by NMR spectroscopy.
کلیدواژه‌ها
Glycerol Ketals؛ Diesel؛ Biodiesel؛ Cetane Number؛ Transesterification
مراجع
  1. Barman SC, Kumar R, Singh GS, et al. Assessment of urban air pollution and its health impact. Journal of Environmental Biology. 2010 Nov 1;31(6):913-20.
  2. Janaun J, Ellis N. Perspectives on biodiesel as a sustainable fuel. Renewable & Sustainable Energy Review. 2010 May 1;14 (4):1312-20. doi.org/10.1016/j.rser.2009.12.011
  3. Meher LC, Vidya D.S, Naik SN. Technical aspects of biodiesel production by transesterification-a review. Renewable & Sustainable Energy Review. 2006 Jun 1; 10(3):248- 68. doi.org/10.1016/j.rser.2004.09.002
  4. Miriam DT, Gonzalo J, Jose AM, Elísabet P, Mario S. Glycerol ketals: Synthesis and profits in biodiesel blends. Fuel. 2012 Apr 1;94:614-16. doi.org/10.1016/j.fuel.2011.11.062
  5. Edgar L, Yiyan L, Lopez DE, Suwannakaran K, Bruce DA, James GJ. Synthesis of biodiesel via acid catalysis. Industrial & Engineering Chemistry Research. 2005 Jan 25;44(14):5353-63. doi.org/10.1021/ie049157g
  6. Nagarhalli MV, Nandedkar VM, Mohite KC. Emission and performance characteristics of Karanga biodiesel and its blends in a CI engine and its economics. ARPN Journal of Engineering and Applied Sciences. 2010 Feb 1;5(2) 52-56.
  7. Nwafor OMI. Emission characteristics of diesel engine operating on rapeseed methyl ester. Renewable Enerergy. 2004 Jun 1;29(1):119-29. doi.org/10.1016/S0960-1481(03)00133-2
  8. Prasad TH, Reddy KHC, Rao MM. Performance and exhaust emissions analysis of a diesel engine using methyl ester of oil with artificial neural network aid. International Journal of Engineering and Technology. 2010 Feb 1;2(1):23-27. doi.org/10.7763/IJET.2010.V2.94
  9. Youngs H, Somerville C. Development of cellulose biofuels. F1000 Biology Reports. 2012 May 2; 4(10):1-11. doi.org/10.3410/B4-10
  10. Krishnakumar J, Venkatachalapathy VSK. Elancheliyan S. Technical aspects of biodiesel production from vegetable oils. Thermal Science. 2008 Dec 1;12(2) 159-69. doi.org/10.2298/TSCI0802159K
  11. Garcez CAG, Vianna JNS. Brazilian Biodiesel Policy: Social and environmental considerations of sustainability. Energy. 2009 May 1;34(5):645-54. doi.org/10.1016/j.energy.2008.11.005
  12. Behr A, Eilting J, Irawadi K, Leschinski J, Lindner F. Improved utilisation of renewable resources: new important derivatives of glycerol. Green Chemistry. 2008 Oct 1;10:13-30.
  13. Zheng Y, Chen X, Shen Y. Commodity chemicals derived from glycerol, an important biorefinery feedstock. Chemical Review. 2008 Oct 1;110:5253-77. doi.org/10.1039/B710561D
  14. Melero JA, Vicente G, Morales G, Paniagua M, Bustamante J. Oxygenated compounds derived from glycerol for biodiesel formulation: influence on EN 14214 quality parameters. Fuel. 2010 Aug1;89:2011-18. doi.org/10.1016/j.fuel.2010.03.042
  15. Noureddini H. Production of oxygenated biodiesel fuel of low cloud point. 2000; US Patent 6015440-A.
  16. Jaecker-Voirol A, Durand I, Hillion G, Delfort B, Montagne X. Glycerin for new biodiesel formulation. Oil & Gas Sciience and Technology. 2008 Aug 1;63:395-04. 196. doi.org/10.2516/ogst:2008033
  17. Rabello CRK, Ferreira YK, Menezes De RB, Menezes De R, Ferreira Y, Rabello C. Production of cetane number increasing additive for diesel fuel, uses glycerine from plants and/or alkenes and/or alkynes. 2009; WO Patent 2008129226-A1.
  18. Delfort B, Durand I, Jaecker A, Lacome T,. Montagne X, Paille F. Diesel fuel compositions with reduced particulate emission, containing glycerol acetal derivatives US. 2004; Patent 2003163949-A1.
  19. Mota CJA, Silva PHR, Gonçalves LCV. Glycerol acetals as anti-freezing additives for biodiesel. Bioresourch Technoogy. 2010 Aug 1;101(15) 6225-29. doi.org/10.1016/j.biortech.2010.02.101
  20. Carolina da Silva XA, Gonçalves LCV, Claudio Mota JA. Water-tolerant zeolite catalyst for the acetalisation of glycerol. Green Chemistry. 2009 Nov 1;11:38-41. doi.org/10.1039/B813564A
  21. Kale H, Benjamin GH. High cetane renewable diesel fuels prepared from bio-based methyl ketones and diols. Sustainable Energy & Fuels. 2018 Feb 1;2:367-71. doi.org/10.1039/C7SE00415J
  22. Claudio JAM, Carolina XAS, Nilton RJ, Jair C, Flavia S. Glycerin derivatives as fuel additives: The addition of glycerol/acetone ketal (solketal) in gasolines. Energy & Fuel. 2010 Mar 1;24(4):2733-36. doi.org/10.1021/ef9015735
  23. Silva MJ, Julio AA, Dorigetto FCS. Solvent free heteropolyacid-catalyzed glycerol ketalization at room temperature. RCS Advances. 2015May 1;55(5):44499-506. doi.org/10.1039/C4RA17090C
  24. Radheshyam RP, Kalpeshgiri AG, Adarsh SB, Kumaresan S, Seung ML, Hari CB. Clay catalysed rapid valorization of glycerol towards cyclic acetals and ketals. RCS Advance. May 1;102(5):83985-996. doi.org/10.1039/C5RA15817F
  25. Malaya RN, Yongsheng Z, Zhongshun Y, Wensheng Q, Hassan SG, Chunbao CX. Catalytic conversion of glycerol for sustainable production of solketal as a fuel additive: a review. Renewable & Sustainable Energy Review. 2016 Apr 1;56:1022-31. doi.org/10.1016/j.rser.2015.12.008
  26. Narinthorn S, Boonyarach K. Synthesis of solketal from glycerol and its reaction with benzyl alcohol. Energy Procedia. 2011 Sep 1;9:63-69. doi.org/10.1016/j.egypro.2011.09.008
  27. Dmitriev GS, Terekhov AV, Zanaveskin LN, Khadzhiev SN, Zanaveskin KL, Maksimov AL. Choice of a catalyst and technological scheme for synthesis of solketal. Russian Journal Appllied Chemistry. 2017 Feb 9;89:1619-24. doi.org/10.1134/S1070427216100094
  28. Terekhov AV, Dmitriev GS, Khadzhiev SN, Zanaveskin LN. Recovery of solketal from reaction products by extraction. Russian Journal Appllied Chemistry. 2016 Jul 15;89:639-43. doi.org/10.1134/S1070427216040182
  29. Varfolomeev SD, Volieva VB, Usachev SV, Belostotskaya IS, Komissarova NL, Malkova AV, Nekhaev AI, Maksimov AL, Makarov GG. Catalytic system for the synthesis of cyclic ketals from glycerol and lower carbonyl compounds (High-octane fuel bioadditives). Biocatalysis. 2011 Apr 26;3:11-14. doi.org/10.1134/S207005041101017X
  30. Eva G, Miriam L, Elena P, Angel G, Julian P. New class of acetal derived from glycerin as a biodiesel fuel component. Energy & Fuel, 2008 Apr 1; 22(8) 4274-80. doi.org/10.1021/ef800477m
  31. George WM, Wayne MS, Erna JB, Subash CB, Eric S, John C. The synthesıs of acetals and ketals of the reduced sugar mannose as fuel system icing inhıbıtors. Petroleum Science Technology. 1997 Apr 25;15(3&4):237-44. doi.org/10.1080/10916469708949654
  32. José IG, Héctor GM, Elísabet P. Glycerol based solvents: synthesis, properties and applications. Green Chemistry. 2014 Apr 1; 3(16):1007-33. doi.org/10.1039/C3GC41857J
  33. Lee HV, Juan JC, Taufiq-Yap YH, Kong PS, Rahman NA. Advancement in heterogeneous base catalyzed technology: An efficient production of biodiesel fuels. 2015 May 26; 7: 032701-46. doi.org/10.1063/1.4919082
  34. Yameen MZ, AlMohamadi H, Naqvi SR, Noor T, Chen WH, Amin NAS. Advances in production & activation of marine macroalgae-derived biochar catalyst for sustainable biodiesel production. 2023 Apr 1; 337, 127215. doi.org/10.1016/j.fuel.2022.127215
  35. Kanit K. A simple method for estimation of cetane index of vegetable oil methyl esters. Journal of the American Oil Chemists' Society. 1986 Apr 1;63:552-53. doi.org/10.1007/BF02645752
  36. Milan LS, Ronald W, Marvın R, Brıan R, Terry T. Application of 13C and 1H Nuclear Magnetic Resonance for the evaluation of cetane rating of middle distillates. Fuel Processing Technology. 1990 Nov 1;26(2):117-34. doi.org/10.1016/0378-3820(90)90016-L
  37. Yanowitz J, Ratcliff MA, McCormick RL, Taylor JD, Murphy MJ/ Compendium of experimental cetane numbers (USA) 2014, 78 p.
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