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Application of Ti3C2(OH)2 MXene Nanosheets as a Potential Adsorbent and Photocatalyst for Degradation of Organic Dye in Aqueous Media | ||
| Pollution | ||
| دوره 9، شماره 2، تیر 2023، صفحه 782-794 اصل مقاله (2.73 M) | ||
| نوع مقاله: Original Research Paper | ||
| شناسه دیجیتال (DOI): 10.22059/poll.2022.351101.1684 | ||
| نویسندگان | ||
| Batool Hasani Khaneghahi1؛ Shiva Dehghan Abkenar* 1؛ Javad Gilnejad2؛ Mohammad Reza Ganjali2؛ Morteza Hosseini3 | ||
| 1Department of Chemistry, Savadkooh Branch, Islamic Azad University, Savadkooh, Iran | ||
| 2Center of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran, Iran | ||
| 3Department of Life Science Engineering, Faculty of New Sciences and Technologies, University of Tehran, Tehran, Iran | ||
| چکیده | ||
| In this work, single layered Ti3C2(OH)2 MXene nanosheets have been successfully prepared through a facile approach by etching Ti3AlC2 with alkaline solution treatment (KOH with minimum amounts of water). The structure and morphology of the produced nanosheets were evaluated through X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) analysis and the chemical composition was determined using an energy dispersion X-ray (EDX) spectrometer. Methylene Blue (MB) as a target pollutant adsorption and photocatalytic degradation tests were subsequently performed to assess the functionalities of hydroxyl-terminated MXene. MB removal using Ti3C2(OH)2 MXene in the dark in 20 minutes achieved an absorption-desorption balance of 51.2%, and then MB was degraded within 80 minutes under UV light irradiation with great efficiency. Our results presented that the powder of as produced exhibited good photocatalytic activity for three cycles photodegradation. The first-order rate constant (k) was calculated to be 0.0372 1/min. About 97% degradation of Methylene Blue dye in the solution was confirmed within 80 min of exposure to ultraviolet light. | ||
| کلیدواژهها | ||
| Methylene Blue؛ Photocatalyst؛ Degradation؛ Adsorbent؛ MXene | ||
| مراجع | ||
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Abdel-Ghani, N. T., El-Chaghaby, G. A., Rawash, E.-S. A. and Lima, E. C. (2019). Magnetic activated carbon nanocomposite from Nigella sativa L. waste (MNSA) for the removal of Coomassie brilliant blue dye from aqueous solution: Statistical design of experiments for optimization of the adsorption conditions. Journal of Advanced Research, 17, 55-63. Abkenar, S. D., Khoobi, M., Tarasi, R., Hosseini, M., Shafiee, A. and Ganjali, M. R. (2015). Fast removal of methylene blue from aqueous solution using magnetic-modified Fe3O4 nanoparticles. Journal of Environmental Engineering, 141(1), 04014049. Abukhadra, M. R., Shaban, M. and Abd El Samad, M. A. (2018). Enhanced photocatalytic removal of Safranin-T dye under sunlight within minute time intervals using heulandite/polyaniline@ nickel oxide composite as a novel photocatalyst. Ecotoxicology and environmental safety, 162, 261-271. Albukhari, S. M., Abdel Salam, M. and Aldawsari, A. M. (2022). Removal of Malachite Green Dye from Water Using MXene (Ti3C2) Nanosheets. Sustainability, 14(10), 5996. Alhabeb, M., Maleski, K., Anasori, B., Lelyukh, P., Clark, L., Sin, S. and Gogotsi, Y. (2017). Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2T x MXene). Chemistry of Materials, 29(18), 7633-7644. Anasori, B., Xie, Y., Beidaghi, M., Lu, J., Hosler, B. C., Hultman, L. and Barsoum, M. W. (2015). Two-dimensional, ordered, double transition metals carbides (MXenes). ACS nano, 9(10), 9507-9516. Dehghan Abkenar, S., Ganjali, M. R., Hossieni, M. and Sadeghpour Karimi, M. (2019). Application of copper vanadate nanoparticles for removal of methylene blue from aqueous solution: kinetics, equilibrium, and thermodynamic studies. Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 38(6), 83-92. Dehghan Abkenar, S., Hosseini, M., Sadeghpour Karimi, M. and Ganjali, M. (2019). Efficient removal of methylene blue from aqueous solution by adsorption on cerium vanadate nanoparticles. Pollution, 5(2), 339-349. Din, M. I., Khalid, R., Najeeb, J. and Hussain, Z. (2021). Fundamentals and photocatalysis of methylene blue dye using various nanocatalytic assemblies- a critical review. Journal of Cleaner Production, 298, 126567. Geravand, M. H. A., Saljoughi, E., Mousavi, S. M. and Kiani, S. (2021). Biodegradable polycaprolactone/MXene nanocomposite nanofiltration membranes for the treatment of dye solutions. Journal of the Taiwan Institute of Chemical Engineers, 128, 124-139. Ghidiu, M., Lukatskaya, M. R., Zhao, M.-Q., Gogotsi, Y. and Barsoum, M. W. (2014). Conductive two-dimensional titanium carbide ‘clay’with high volumetric capacitance. Nature, 516(7529), 78-81. Hajiaghababaei, L., Abozari, S., Badiei, A., Zarabadi Poor, P., Dehghan Abkenar, Sh., Ganjali, M. R. and Mohammadi Ziarani, G. (2017). Amino Ethyl-Functionalized SBA-15: A promising adsorbent for anionic and cationic dyes removal. Iran. J. Chem. Chem. Eng., 36, 97-108. Khazaei, M., Arai, M., Sasaki, T., Chung, C. Y., Venkataramanan, N. S., Estili, M. and Kawazoe, Y. (2013). Novel electronic and magnetic properties of two‐dimensional transition metal carbides and nitrides. Advanced Functional Materials, 23(17), 2185-2192. Khazaei, M., Ranjbar, A., Arai, M., Sasaki, T. and Yunoki, S. (2017). Electronic properties and applications of MXenes: a theoretical review. Journal of Materials Chemistry C, 5(10), 2488-2503. Kumar, K., Chitkara, M., Sandhu, I. S., Mehta, D. and Kumar, S. (2014). Photocatalytic, optical and magnetic properties of Fe-doped ZnO nanoparticles prepared by chemical route. Journal of Alloys and Compounds, 588, 681-689. Li, G., Tan, L., Zhang, Y., Wu, B. and Li, L. (2017). Highly efficiently delaminated single-layered MXene nanosheets with large lateral size. Langmuir, 33(36), 9000-9006. Li, X., Bai, Y., Shi, X., Su, N., Nie, G., Zhang, R. and Ye, L. (2021). Applications of MXene (Ti3C2Tx) in photocatalysis: A review. Materials Advances, 2(5), 1570-1594. Munyai, S., Tetana, Z., Mathipa, M., Ntsendwana, B. and Hintsho-Mbita, N. (2021). Green synthesis of Cadmium Sulphide nanoparticles for the photodegradation of Malachite green dye, Sulfisoxazole and removal of bacteria. Optik, 247, 167851. Naguib, M., Mashtalir, O., Carle, J., Presser, V., Lu, J., Hultman, L. and Barsoum, M. W. (2012). Two-dimensional transition metal carbides. ACS nano, 6(2), 1322-1331. Naguib, M., Mochalin, V. N., Barsoum, M. W. and Gogotsi, Y. (2014). 25th anniversary article: MXenes: a new family of two‐dimensional materials. Advanced materials, 26(7), 992-1005. Pang, Y. L., Koe, A. Z. Y., Chan, Y. Y., Lim, S. and Chong, W. C. (2022). Enhanced Sonocatalytic Performance of Non-Metal Graphitic Carbon Nitride (g-C3N4)/Coconut Shell Husk Derived-Carbon Composite. Sustainability, 14(6), 3244. Pebdeni, A. B., Khurshid, C. A., Abkenar, S. D. and Hosseini, M. (2021). Green Synthesis of Carbon Quantum Dots Doped on Nickel Oxide Nanoparticles as Recyclable Visible Light Photocatalysts for Enhanced Degradation of Malachite Green. ChemistrySelect, 6(20), 5034-5042. Qu, J., Teng, D., Zhang, X., Yang, Q., Li, P. and Cao, Y. (2022). Preparation and regulation of two-dimensional Ti3C2Tx MXene for enhanced adsorption–photocatalytic degradation of organic dyes in wastewater. Ceramics International, 48(10), 14451-14459. Tamara K. H. and Nidaa A. J. (2019). Removal of Crysta Violet and Methylene Blue from Synthetic Industerial Wastewater using Fennel Seed as an Adsorbent, Journal of Engineering Science and Technology, 14(5), 2947 - 2963. Tiwari, G., Singh, H. and Tripathi, R. (2003). Present status of solar distillation. Solar energy, 75(5), 367-373. Tran, N. M., Ta, Q. T. H., Sreedhar, A. and Noh, J.-S. (2021). Ti3C2Tx MXene playing as a strong methylene blue adsorbent in wastewater. Applied Surface Science, 537, 148006. Wei, Z., Peigen, Z., Wubian, T., Xia, Q., Yamei, Z. and ZhengMing, S. (2018). Alkali treated Ti3C2Tx MXenes and their dye adsorption performance. Materials Chemistry and Physics, 206, 270-276. Wu, K., Shi, M., Pan, X., Zhang, J., Zhang, X., Shen, T. and Tian, Y. (2022). Decolourization and biodegradation of methylene blue dye by a ligninolytic enzyme-producing Bacillus thuringiensis: Degradation products and pathway. Enzyme and Microbial Technology, 156, 109999. Xie, Y., Huang, J., Dong, H., Wu, T., Yu, L., Liu, G. and Yu, Y. (2020). Insight into performance and mechanism of tea polyphenols and ferric ions on reductive decolorization of malachite green cationic dye under moderate conditions. Journal of environmental management, 261, 110226. | ||
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