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Ahmadian, Zahra, Azad, Mohammadi, Mohammadi, Somayeh, Mortazavi, Yadollah, Khodadadi, Abbas-Ali. (1401). The effect of ball-milling parameters on the structures of Ti3AlC2 MAX phase and resultant Ti3C2Tx MXene. , 55(2), 112-121. doi: 10.22059/jufgnsm.2022.02.03
Zahra Ahmadian; Mohammadi Javad Azad; Somayeh Mohammadi; Yadollah Mortazavi; Abbas-Ali Khodadadi. "The effect of ball-milling parameters on the structures of Ti3AlC2 MAX phase and resultant Ti3C2Tx MXene". , 55, 2, 1401, 112-121. doi: 10.22059/jufgnsm.2022.02.03
Ahmadian, Zahra, Azad, Mohammadi, Mohammadi, Somayeh, Mortazavi, Yadollah, Khodadadi, Abbas-Ali. (1401). 'The effect of ball-milling parameters on the structures of Ti3AlC2 MAX phase and resultant Ti3C2Tx MXene', , 55(2), pp. 112-121. doi: 10.22059/jufgnsm.2022.02.03
Ahmadian, Zahra, Azad, Mohammadi, Mohammadi, Somayeh, Mortazavi, Yadollah, Khodadadi, Abbas-Ali. The effect of ball-milling parameters on the structures of Ti3AlC2 MAX phase and resultant Ti3C2Tx MXene. , 1401; 55(2): 112-121. doi: 10.22059/jufgnsm.2022.02.03

The effect of ball-milling parameters on the structures of Ti3AlC2 MAX phase and resultant Ti3C2Tx MXene

Journal of Ultrafine Grained and Nanostructured Materials
مقاله 3، دوره 55، شماره 2، اسفند 2022، صفحه 112-121    اصل مقاله (1.12 M)
نوع مقاله: Research Paper
شناسه دیجیتال (DOI): 10.22059/jufgnsm.2022.02.03
نویسندگان
Zahra Ahmadian1؛ Mohammadi Javad Azad1؛ Somayeh Mohammadi* 2؛ Yadollah Mortazavi1؛ Abbas-Ali Khodadadi1
1Catalysis and Nanostructured Materials Research Laboratory, School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran
2School of Engineering science, College of Engineering, University of Tehran, Tehran, Iran
چکیده
In this work, the effects of ball-milling parameters on the structure of the Ti3AlC2 MAX-phase, the precursor of Ti3C2Tx MXene, is investigated. To clarify this effect, three approaches with different milling parameters were used to synthesize Ti3AlC2 MAX-phase. In all approaches, the initial elements with the proportion of 3Ti:1.3Al:1.9C were milled at different milling times, intervals, and rotating speeds. The resulting powders were sintered in a SPS furnace with the sintering temperature of 1000-1150 °C.  According to our observation, emerging intermediate Ti and Al compounds in the milling process is the key point for forming the final Ti3AlC2 since such compounds would assist the formation of MAX-phase in the SPS process. Moreover, the temperature increment during the milling process is necessary for the formation of such intermediate compounds. This condition can be achieved when the ratio of intervals to milling times in each milling step is low enough (5 min per 30 min) or the rotating speed is high enough (around 600 rpm). The Al layers in Ti3AlC2 MAX-phase obtained in each approach are etched by HF solution to reveal the difference between the resultant Ti3C2Tx MXene nanolayers. Our characterization suggests that ball-milling at 400 rpm for 18 hours with 5-minute intervals produces the highest quality MAX-phase and MXene.
کلیدواژه‌ها
ball-milling؛ Ti3AlC2 MAX-phase؛ Ti3C2Tx MXene nanolayers؛ SPS method
مراجع
  1. Pan Z, Cao F, Hu X, Ji X. A facile method for synthesizing CuS decorated Ti3C2 MXene with enhanced performance for asymmetric supercapacitors. Journal of Materials Chemistry A. 2019;7(15):8984-92.
  2. Ghosh NC, Harimkar SP. Consolidation and synthesis of MAX phases by Spark Plasma Sintering (SPS): a review. Advances in Science and Technology of Mn+1AXn Phases: Elsevier; 2012. p. 47-80.
  3. Zhao L, Wang K, Wei W, Wang L, Han W. High‐performance flexible sensing devices based on polyaniline/MXene nanocomposites. InfoMat. 2019;1(3):407-16.
  4. Shuck CE, Han M, Maleski K, Hantanasirisakul K, Kim SJ, Choi J, Reil WE, Gogotsi Y. Effect of Ti3AlC2 MAX phase on structure and properties of resultant Ti3C2T x MXene. ACS Applied Nano Materials. 2019 May 13;2(6):3368-76.
  5. Naguib M, Kurtoglu M, Presser V, Lu J, Niu J, Heon M, et al. Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2. Advanced Materials. 2011;23(37):4248-53.
  6. Halim J, Lukatskaya MR, Cook KM, Lu J, Smith CR, Näslund L-Å, et al. Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films. Chem Mater. 2014;26(7):2374-81.
  7. Ghidiu M, Lukatskaya MR, Zhao M-Q, Gogotsi Y, Barsoum MW. Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance. Nature. 2014;516(7529):78-81.
  8. Shahzad F, Alhabeb M, Hatter CB, Anasori B, Man Hong S, Koo CM, et al. Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science. 2016;353(6304):1137-40.
  9. Pietzka MA, Schuster JC. Summary of constitutional data on the Aluminum-Carbon-Titanium system. Journal of Phase Equilibria. 1994;15(4):392-400.
  10. Tzenov, N.V. and M.W. Barsoum, Synthesis and characterization of Ti3AlC2. Journal of the American Ceramic Society, 2000. 83(4): p. 825-832.
  11. Wang X, Zhou Y. Solid–liquid reaction synthesis of layered machinable Ti3AlC2 ceramic. Journal of Materials Chemistry. 2002;12(3):455-60.
  12. Khoptiar Y, Gotman I, Gutmanas EY. Pressure-Assisted Combustion Synthesis of Dense Layered Ti3AlC2 and its Mechanical Properties. Journal of the American Ceramic Society. 2005;88(1):28-33.
  13. Ge Z, Chen K, Guo J, Zhou H, Ferreira JMF. Combustion synthesis of ternary carbide Ti3AlC2 in Ti–Al–C system. Journal of the European Ceramic Society. 2003;23(3):567-74.
  14. Yunus M, Kumar R, Maji BC, Krishnan M. An optimized method for synthesizing phase-pure Ti3AlC2 MAX-phase through spark plasma sintering. Journal of the European Ceramic Society. 2022;42(2):354-63.
  15. Syrtanov M, Kashkarov E, Murashkina T, Travitzky N. Spark Plasma Sintering of Paper-Derived Ti<sub>3</sub>AlC<sub>2</sub>-Based Composites: Influence of Sintering Temperature. Materials Science Forum. 2021;1016:1790-6.
  16. Zhou W, Mei B, Zhu J, Hong X. Synthesis of high-purity Ti3SiC2 and Ti3AlC2 by spark plasma sintering (SPS) technique. Journal of Materials Science. 2005;40(8):2099-100.
  17. Zhou A, Wang C-A, Hunag Y. Journal of Materials Science. 2003;38(14):3111-5.
  18. Apal’kova GD. Effect of Nano-Dispersed Iron Oxide Additions on Carbon Refractory Density Formation. Refractories and Industrial Ceramics. 2019;59(6):609-11.
  19. Yang C, Jin S, Liang B, Liu G, Duan L, Jia S. Synthesis of Ti3AlC2 by spark plasma sintering of mechanically milled 3Ti/xAl/2C powder mixtures. Journal of Alloys and Compounds. 2009;472(1-2):79-83.
  20. Gao L, Wang HZ, Hong JS, Miyamoto H, Miyamoto K, Nishikawa Y, et al. Mechanical Properties and Microstructure of Nano-SiC–Al2O3 Composites Densified by Spark Plasma Sintering. Journal of the European Ceramic Society. 1999;19(5):609-13.
  21. Perera DS, Tokita M, Moricca S. Comparative study of fabrication of Si3N4/SiC composites by spark plasma sintering and hot isostatic pressing. Journal of the European Ceramic Society. 1998;18(4):401-4.
  22. von Treifeldt JE, Firestein KL, Fernando JFS, Zhang C, Siriwardena DP, Lewis C-EM, et al. The effect of Ti3AlC2 MAX phase synthetic history on the structure and electrochemical properties of resultant Ti3C2 MXenes. Materials & Design. 2021;199:109403.
  23. Li S-B, Zhai H-X, Bei G-P, Zhou Y, Zhang Z-L. Synthesis and microstructure of Ti3AlC2 by mechanically activated sintering of elemental powders. Ceramics International. 2007;33(2):169-73.
  24. Zou Y, Sun Z, Hashimoto H, Tada S. Low temperature synthesis of single-phase Ti3AlC2 through reactive sintering Ti/Al/C powders. Materials Science and Engineering: A. 2008;473(1-2):90-5.
  25. Yang C, Jin SZ, Liang BY, Jia SS. Low-temperature synthesis of high-purity Ti3AlC2 by MA-SPS technique. Journal of the European Ceramic Society. 2009;29(1):181-5.
  26. Zhu JF, Qi GQ, Yang HB, Wang F. Synthesis of Ti3AlC2 Powder by High Energy Ball Milling and High Temperature Heat Treatment. InMaterials Science Forum 2010 (Vol. 658, pp. 181-184). Trans Tech Publications Ltd.
  27. Zhu JF, Qi GQ, Yang HB, Wang F. Synthesis of Ti3AlC2 Powder by High Energy Ball Milling and High Temperature Heat Treatment. InMaterials Science Forum 2010 (Vol. 658, pp. 181-184). Trans Tech Publications Ltd.
  28. Ronnasi B, Mahmoodian M, Mohammadi S, Yasoubi M, Sanaee Z. ⍺-NSA doped PPy @ Ti3C2Tx hybrid material as a high-performance supercapacitor electrode. Journal of Materials Research. 2022;37(22):3965-75.
  29. Chen B, Feng A, Liu K, Wu J, Yu Y, Song L. Subsize Ti3C2T derived from molten-salt synthesized Ti3AlC2 for enhanced capacitive deionization. Ceramics International. 2021;47(3):3665-70.
  30. Gao L, Han T, Guo Z, Zhang X, Pan D, Zhou S, et al. Preparation and performance of MAX phase Ti3AlC2 by in-situ reaction of Ti-Al-C system. Advanced Powder Technology. 2020;31(8):3533-9.
  31. Munir S, Rasheed A, Rasheed T, Ayman I, Ajmal S, Rehman A, et al. Exploring the Influence of Critical Parameters for the Effective Synthesis of High-Quality 2D MXene. ACS Omega. 2020;5(41):26845-54.
 

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