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هیومیفیکاسیون لیگنایت در فاز جامد جهت فعالسازی ترکیبات نیترو-هیومیکی از طریق اکسیداسیون ازن: ارزیابی عملکرد هیومیفیکاسیون و تبدیل نیتروژن در فرآیند | ||
تحقیقات آب و خاک ایران | ||
دوره 53، شماره 5، مرداد 1401، صفحه 917-936 اصل مقاله (2.1 M) | ||
نوع مقاله: مقاله پژوهشی | ||
شناسه دیجیتال (DOI): 10.22059/ijswr.2022.340128.669223 | ||
نویسندگان | ||
احسان سرلکی1؛ محمد حسین کیان مهر* 2؛ علی ماشاءالله کرمانی3 | ||
1دانشجوی دکتری مهندسی مکانیک بیوسیستم، گروه مهندسی فنی کشاورزی، پردیس ابوریحان، دانشگاه تهران، تهران، ایران. | ||
2گروه مهندسی بیوسیستم. پردیس ابوریحان . دانشگاه تهران | ||
3استادیار، گروه فنی کشاورزی، پردیس ابوریحان، دانشگاه تهران، تهران، ایران. | ||
چکیده | ||
این پژوهش اولین تلاش در هیومیفیکاسیون فاز جامد لیگنایت جهت فعالسازی ترکیبات نیترو-هیومیکی (NHSs) در راستای بهبود کاربرد لیگنایتها در کشاورزی و محیط زیست است. از اکسیداسیون ازن، افزودنیهای اوره و KOH بهترتیب برای تسریع فرآیند هیومیفیکاسیون، غنیسازی نیتروژن و عامل فعالسازی هیومیک اسیدها استفاده شد. بهمنظور بررسی عملکرد هیومیفیکاسیون فاز جامد لیگنایت، شاخصهایی از قبیل محتوای هیومیک اسید کل (THA)، هیومیک اسید محلول در آب (WHA)، محتوای نیتروژن و اکسیژن، نسبت C/N، درجه اکسیداسیون (O/C) حاصل از آنالیز عناصر اصلی CHNOS و محتوای گروههای عاملی کربوکسیلی و فنولی هیدروکسیل ارزیابی شدند. جهت تأیید تغییرات گروههای عاملی حاوی نیتروژن و اکسیژن و همچنین تبدیل مؤثر نیتروژن در فرآیند هیومیفیکاسیون از طیفسنجی FT-IR و آنالیز درصد توزیع انواع نیتروژنهای تثبیتشده استفاده شد. آزمایشها و جمعآوری دادههای این پژوهش در سال 1400 در دانشکدگان ابوریحان-دانشگاه تهران و در آزمایشگاههای گروه مهندسی بیوسیستم انجام شده است. در ادامه، روش سطح پاسخ مبتنی بر طرح مرکب مرکزی (CCD-RSM) برای تعیین شرایط بهینه استفاده و مدلهای ریاضی برای پیشبینی دقیق تغییرات دو پاسخ THA و WHA توسعه داده شد. تحت شرایط بهینه 8 گرم بر ساعت نرخ ازندهی، 15 دقیقه زمان اکسیداسیون، 85/14 درصد وزنی KOH و 30 درصد وزنی اوره، مقدار THA و WHA بهترتیب 02/69 و 32/53 درصد حاصل شد که بهطور قابل توجهی بیشتر از نمونه کنترل (بدون ازندهی و اوره) بهترتیب 30 و 7 درصد بود. توزیع یکنواخت فرمهای تثبیتشده نیتروژن در ترکیبات NHSs نشان داد که 47 درصد از مقدار نیتروژن کل به فرم نیتروژن آمونیومی، 16 درصد به فرم نیتروژن آمید و 37 درصد به فرم نیتروژن آلی پیوندی با اتصالات بسیار قوی است. مقدار گروههای فنولی 71/85 درصد و مقدار گروههای کربوکسیلی 87/215 درصد در اثر هیومیفیکاسیون ازن افزایش نشان دادند. فرآیند بهینهسازی شده منجر به بهبود شاخصهای کیفی از جمله کربن کمتر، نیتروژن بیشتر و در نتیجه نسبت C/N کمتر، نسبت O/C بیشتر، کربن آروماتیک کمتر، کربن آلیفاتیک و کربوکسیلی بیشتر برای ترکیبات NHSs شد. | ||
کلیدواژهها | ||
فعالسازی لیگنایت؛ هیومیک اسید؛ اکسیداسیون ازن؛ هیومیفیکاسیون تسریعیافته | ||
مراجع | ||
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