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تأثیر لجن فاضلاب و بیوچارهای حاصل از آن بر قابلیت استفاده و ویژگیهای آزادشدن مس در یک خاک آهکی آلوده | ||
تحقیقات آب و خاک ایران | ||
دوره 51، شماره 10، دی 1399، صفحه 2455-2468 اصل مقاله (1.05 M) | ||
نوع مقاله: مقاله پژوهشی | ||
شناسه دیجیتال (DOI): 10.22059/ijswr.2020.293568.668418 | ||
نویسندگان | ||
مرتضی شیرمحمدی* 1؛ علیرضا حسین پور1؛ حمیدرضا متقیان2 | ||
1گروه علوم و مهندسی خاک، دانشکده کشاورزی، دانشگاه شهرکرد، شهرکرد، ایران | ||
2گروه علوم و مهندسی خاک، دانشکده کشاورزی، دانشگاه شهرکرد، شهرکرد، ایران | ||
چکیده | ||
هدف این پژوهش بررسی تأثیر سطوح مختلف لجن فاضلاب و همچنین بیوچار آن بر قابلیت استفاده و سینتیک آزادشدن مس در یک خاک آهکی آلوده به مس بود. برای این منظور لجن فاضلاب و بیوچار حاصل از آن در دو دمای تولید بیوچار شامل 400 و 600 درجه سلسیوس در سه سطح صفر، 5/0 و 1 درصد وزنی/وزنی به یک خاک آهکی آلوده به مس افزوده و به مدت 5 ماه خوابانده شدند. نمونههای خاک به روش عصارهگیری متوالی و با استفاده از عصارهگیر دی تی پی آ (DTPA-TEA) در دورههای زمانی 1 تا 504 ساعت عصارهگیری شدند. نتایج نشان داد که تیمار لجن فاضلاب در هر دو سطح باعث افزایش معنیدار (05/0p <) آزاد شدن مس نسبت به خاک شاهد شد، درحالیکه مقدار مس آزادشده در تیمارهای بیوچار 400 و همچنین بیوچار 600 در هر دو سطح به طوری معنیداری (05/0p <) نسبت به خاک شاهد کمتر بود. مقدار مس آزادشده در خاک تیمار شده با 1 درصد بیوچار 600 نسبت به خاک شاهد 2/54 درصد کاهش یافت. مقایسه ضرایب سرعت معادلات سینتیکی نشان داد که بیشترین و کمترین سرعت آزاد شدن مس بهترتیب در تیمارهای 1 درصد لجن فاضلاب و 1 درصد بیوچار 600 بود. بطور کلی نتایج این تحقیق نشان داد که تبدیل لجن فاضلاب در یک دمای گرماکافت بهینه (در این مطالعه دمای 600 درجه سلسیوس) به بیوچار، علاوه بر اینکه راهکار مناسبی برای مدیریت لجن فاضلاب است، میتواند در تثبیت مس و اصلاح خاکهای آلوده به مس نیز مفید باشد. | ||
کلیدواژهها | ||
عصارهگیر دی تی پی ا؛ سینتیک آزاد شدن؛ بیوچار؛ دمای گرماکافت | ||
مراجع | ||
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