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Hoveidi, H., Sid Kalal, H., Nabi Bidhendi, G., Rashedi, H., Vafaei Mehr, D.. (1392). Electrochemical Behavior and the Determination of Furan in Beverage Samples Using Glassy Carbon Electrode. , 7(3), 615-622. doi: 10.22059/ijer.2013.641
H. Hoveidi; H. Sid Kalal; G. Nabi Bidhendi; H. Rashedi; D. Vafaei Mehr. "Electrochemical Behavior and the Determination of Furan in Beverage Samples Using Glassy Carbon Electrode". , 7, 3, 1392, 615-622. doi: 10.22059/ijer.2013.641
Hoveidi, H., Sid Kalal, H., Nabi Bidhendi, G., Rashedi, H., Vafaei Mehr, D.. (1392). 'Electrochemical Behavior and the Determination of Furan in Beverage Samples Using Glassy Carbon Electrode', , 7(3), pp. 615-622. doi: 10.22059/ijer.2013.641
Hoveidi, H., Sid Kalal, H., Nabi Bidhendi, G., Rashedi, H., Vafaei Mehr, D.. Electrochemical Behavior and the Determination of Furan in Beverage Samples Using Glassy Carbon Electrode. , 1392; 7(3): 615-622. doi: 10.22059/ijer.2013.641

Electrochemical Behavior and the Determination of Furan in Beverage Samples Using Glassy Carbon Electrode

International Journal of Environmental Research
مقاله 10، دوره 7، شماره 3، مهر 2013، صفحه 615-622    اصل مقاله (253.99 K)
نوع مقاله: Original Research Paper
شناسه دیجیتال (DOI): 10.22059/ijer.2013.641
نویسندگان
H. Hoveidi1؛ H. Sid Kalal* 2؛ G. Nabi Bidhendi1؛ H. Rashedi3؛ D. Vafaei Mehr4
1Graduate Faculty of Environment, University of Tehran, Tehran, Iran
2NFCRS, Nuclear Science and Technology Research Institute, AEOI, P.O. Box 11365-3486, Tehran, Iran
3Biotechnology Group School of chemical Engineering College of Engineering, University of Tehran P.o.Box:11155-4563,Tehran, Iran
4University of Tehran, Aras International Campus, Aras, Iran
چکیده
Furan is a possible human carcinogen in many types of foods. A new and sensitive electro
analytical method for determination of furan has been developed and validated. The best condition for
electrochemical response was obtained with 0.1 M britton-rabinson buffer solution (pH=5) a glassy carbon
electrode (GCE) was used as the working electrode, a Ag/AgCl/ KCl(sat.) electrode served as the reference
electrode, and a platinum wire as the auxiliary electrode under the Differential Pulse Voltammetry (DPV)
mode. The peak current obtained from DPV was linearly dependent on the Furan concentration in the range
12–360 μM (0.81–24.5 ppm) with correlation coefficients of 0.999 and a limit of detection (LOD) of 3 μM
(0.2 ppm) and limit of quantification (LOQ) of 10 μM (0.68 ppm) were calculated, respectively. The values
of the electron-transfer coefficient (α) involved in the rate determining step calculated from the linear plots of Ep against ln (ν) in the pH range investigated were 0.8 confirming the irreversible nature of the oxidation peak. The reproducibility of the method was tested by analyzing 10 samples containing 30 μM of Furan. The RSD % of the method thus obtained was 3.0 % which showed excellent reproducibility for this developed methods.
کلیدواژه‌ها
Furan؛ Electrochemical studies؛ Differential pulse voltammetry؛ Beverage Samples
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