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. (1369). A STUDY OF THE SILYLATION REACTION OF CYANOEPOXIDES WITH TRIMETHYLCHLOROSILANE IN THE PRESENCE OF MAGNESIUM. , 1(3), -.
. "A STUDY OF THE SILYLATION REACTION OF CYANOEPOXIDES WITH TRIMETHYLCHLOROSILANE IN THE PRESENCE OF MAGNESIUM". , 1, 3, 1369, -.
. (1369). 'A STUDY OF THE SILYLATION REACTION OF CYANOEPOXIDES WITH TRIMETHYLCHLOROSILANE IN THE PRESENCE OF MAGNESIUM', , 1(3), pp. -.
. A STUDY OF THE SILYLATION REACTION OF CYANOEPOXIDES WITH TRIMETHYLCHLOROSILANE IN THE PRESENCE OF MAGNESIUM. , 1369; 1(3): -.

A STUDY OF THE SILYLATION REACTION OF CYANOEPOXIDES WITH TRIMETHYLCHLOROSILANE IN THE PRESENCE OF MAGNESIUM

Journal of Sciences, Islamic Republic of Iran
مقاله 5، دوره 1، شماره 3، شهریور 1990    اصل مقاله (176.8 K)
چکیده
In the presence of magnesium and hexamethylphosphorictriamide,
HMPT, trimethylchlorosilane, TMS-C1, reacts with cyanoepoxides to give
related compounds. Ring cleavage at ? - position of cyanoepoxide, 1,
followed by the addition of two trimethylsilyl groups leads to 2 then
substitution of OSiMei by trimethylsilyl or H takes place to give ?, ? -
bis (trimethylsilyl) nitrile or ? - trimethylsilylnitrile, respectively. Silylation
reaction of cyanoepoxide 4 gives compounds 5 and 6, but silylation
of 9 gives only ? - monosilylated derivative 10. Silylation of a, ?-
diphenylcyanoepoxide, 11, leads to polysilylated products, by participation
of both nitrile and epoxide functions
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