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. (1372). A KINETIC STUDY OF THE DECOMPOSITION OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH ALCOHOLS. , 4(4), -.
. "A KINETIC STUDY OF THE DECOMPOSITION OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH ALCOHOLS". , 4, 4, 1372, -.
. (1372). 'A KINETIC STUDY OF THE DECOMPOSITION OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH ALCOHOLS', , 4(4), pp. -.
. A KINETIC STUDY OF THE DECOMPOSITION OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH ALCOHOLS. , 1372; 4(4): -.

A KINETIC STUDY OF THE DECOMPOSITION OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH ALCOHOLS

Journal of Sciences, Islamic Republic of Iran
مقاله 6، دوره 4، شماره 4، اسفند 1993    اصل مقاله (380.48 K)
چکیده
A kinetic study of the decomposition of pyridine chromium peroxide with
methanol, ethanol, propanol and isopropanol has been made over the temperature
range 25 to 40°C. It is found that the ligand exchange stage is the rate determining step in the oxidation process. The activation parameters E , ?H‡ and ?S‡ for the reactions are determined. It is believed that the peroxide linkage is primarily responseble for the oxidation process
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