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SYNTHESIS OF ?-PYRONEIMINE N-OXIDE A NOVEL NITRONE WITH ELECTRON RELEASING SUBSTITUENT | ||
Journal of Sciences, Islamic Republic of Iran | ||
مقاله 7، دوره 8، شماره 1، خرداد 1997 اصل مقاله (212.76 K) | ||
چکیده | ||
N-Oxidation of 1,4-dihydro-2,6-dimethyl-1- phenyliminopyridine (7) with several peracids was attempted. The main compound obtained was l-phenyl- 2,6-dimethyl-4-pyridone (8), instead of the expected N-oxide (2). The reaction of phenylhydroxylamine with dimthylrnethoxypyroxonium perchlorate, however, successfully gave the N-oxide (3), which belongs to a class of nitrones in which the diazomethine N-oxide group is conjugated with an electron releasing center. | ||
عنوان مقاله [English] | ||
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چکیده [English] | ||
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آمار تعداد مشاهده مقاله: 903 تعداد دریافت فایل اصل مقاله: 885 |