مطالعه سنتیک و ترمودینامیک جذب مس و روی از محلول‌های آبی با استفاده از لئوناردیت: مدلسازی با استفاده از روش سطح پاسخ

Alemu, A., Lemma, B., & Gabbiye, N. (2019). Adsorption of chromium (III) from aqueous solution using vesicular basalt rock. Cogent Environmental Science, 5(1), 1650416.

Al-Degs, A., Kharasheh, M.A.M., & Tutunji, M.F. (2001). Sorption of lead ions on diatomite and    manganes oxides modified diatomite. Water Research, 35, 3724-3728.

Arias, F., & Sen, T.K. (2009). Removal of Zinc metal ion (Zn2+) from its aqueous solution by kaolin clay mineral: a kinetic and equilibrium study. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 348(1-3), 100-108.

Arslan, H., Eskikaya, O., Bilici, Z., Dizge, N., & Balakrishnan, D. (2022). Comparison of Cr (VI) adsorption and photocatalytic reduction efficiency using leonardite powder. Chemosphere, 300, 134492.

Azadian, M., & Ghanadzadeh Gilani, H. (2023). Adsorption of Cu²⁺, Cd²⁺, and Zn²⁺ by engineered biochar: Preparation, characterization, and adsorption properties. Environmental Progress & Sustainable Energy, 42(4), e14088.

Asamoah-Ntow, J., Kyei, S.K., Azanu, D., & Kabange, R.S. (2025). Integrated assessment of heavy metal contamination and health risks in irrigation water, soil, and vegetables along the Dankran River, Bekwai Municipality, Ghana. Chemosphere, 388, 144690.

Ávila, F.G., Cabrera-Sumba, J., Valdez-Pilataxi, S., Villalta-Chungata, J., Valdiviezo-Gonzales, L., & Arnedo, C.A. (2025). Removal of heavy metals in industrial wastewater using adsorption technology: Efficiency and influencing factors. Cleaner Engineering and Technology, 24, 100879.

Bai, C., Zhang, H., luo, Q., Ye, X., Liu, H., Li, Q., Li, J., & Wu, Z. (2023). Boron separation by adsorption and flotation with Mg-Al-LDHs and SDBS from aqueous solution. Chinese Journal of Chemical Engineering, 4, 34-65.

Bazhar, K., Fardioui, M., Bensalah, J., Houmia, I., Kaibous, N., & Guedira, T. (2025). Adsorption performance of heavy metals Co²⁺, Cu²⁺ and Zn²⁺ contained in aqueous solutions by two types of clay: A kinetic study, mathematical and thermodynamic modelling. Journal of the Indian Chemical Society, 102(12), 102241.

Bullen, J.C., Saleesongsom, S., Gallagher, K., & Weiss, D.J. (2021). A revised pseudo-second-order kinetic model for adsorption, sensitive to changes in adsorbate and adsorbent concentrations. Langmuir, 37(10), 3189-3201.

Canpolat, M., & Altunkaynak, Y. (2024). Isotherm, kinetic, and thermodynamic studies of adsorption of copper (II) and nickel (II) ions using low-cost treated orange peel from aqueous solutions. Environmental Progress & Sustainable Energy, 43(5), e14509.

Chu, S., Feng, X., Liu, C., Wu, H., & Liu, X. (2023). Advances in Chelating Resins for Adsorption of Heavy Metal Ions. Industrial & Engineering Chemistry Research, 62(16), 31-52.

Chammui, Y., Sooksamiti, P., Naksata, W., Thiansem, S., & Arqueropanyo, O. A. (2014). Removal of arsenic from aqueous solution by adsorption on Leonardite. Chemical Engineering Journal, 240, 202-210.

Dae, W.C., & Young, H.K. (2005). Chromium (VI) removal in a semi continues process of hallow fiber membrane with organic extractants. Journal of Chemical Engineering, 22(4), 894-898.

Din, M.I., Mujahid, A., Bock, U., Khalid, R., & Hussain, Z. (2024). A kinetic and thermodynamic investigation for adsorption of cadmium (ii) ions on the microwave modified sugar cane bagasse. Desalination and Water Treatment, 317, 100194.

Fagbohun, T.R., Okechukwu, V.O., Adelusi, O.A., & Okonkwo, J.O. (2025). Comparative systematic review of low-cost adsorbents for fluoride and heavy metal removal in rural water supplies in South Africa (1 January 2000 – 30 June 2025). Frontiers in Environmental Science, 13, 1718081.

Fakhre, N.A., & Ibrahim, B.M. (2018). The use of new chemically modified cellulose for heavy metal ion adsorption. Journal of Hazardous Materials, 343, 324–331.

Fan, X., Liu, H., Anang, E., & Ren, D. (2021). Effects of Electronegativity and Hydration Energy on the Selective Adsorption of Heavy Metal Ions by Synthetic NaX Zeolite. Materials, 14(15), 4066.

Gode, F., & Pehlivan, E. (2005). Removal of Cr (VI) from aqueous solution by two Lewatit-anion exchange resins. Journal of Hazardous Materials, 119(1-3), 175–182.

Giles, C.H., Smith, D., & Huitson, A. (1974). A general treatment and classification of the adsorption solute isotherm. I. Theoretical. Journal of Colloid and Interface Science, 47(3), 755–765.

Hayes, M.H.B., & Swift, R.S. (2020). Vindication of humic substances as a key component of organic matter in soil and water. Advances in Agronomy, 163, 1-37.

Ho, Y.S., & McKay, G. (1999). Comparative sorption kinetic studies of dye and aromatic compounds onto fly ash. Journal of Environmental Science and Health, Part A, 34(5), 1179-1204.

Ho, Y.S., & McKay, G. (2002). Application of kinetic models to the sorption of copper (II) on to peat. Adsorption Science & Technology, 20(8), 797–815.

Iqbal, Z., Tanweer, M.S., & Alam, M. (2022). Recent advances in adsorptive removal of wastewater pollutants by chemically modified metal oxides: A review. Journal of Water Process Engineering, 46, 102641.

Jaycock, M.J., & Parfitt, G.D. (1981). Chemistry of Interfaces. Ellis Horwood Ltd.

Jabłońska, B., Jabłoński, P., & Gęga, J. (2025). Kinetics and thermodynamics of Pb(II), Zn(II), and Cd(II) adsorption from aqueous solutions onto activated biochar obtained from tobacco waste. Materials, 18(10), 2324.

Jaycock, M.J., & Parfitt, G.D. (1981). Chemistry of Interfaces. Ellis Horwood Ltd.

Joo, J.C., Go, H., Shackelford, C.D., Nam, K., Moon, H.S., Choi, J., & Kim, J. (2025). Remediating zinc-contaminated groundwater with calcium polysulfide using model porous media and simulated groundwater. Journal of Hazardous Materials, 491, 137840.

Juang, R.S., & Chen, M.L. (1997). Application of the Elovich equation to the kinetics of metal sorption with solvent-impregnated resins. Industrial & Engineering Chemistry Research, 36(3), 813–820.

Khoshraftar, Z., Masoumi, H., & Ghaemi, A. (2023). Experimental, response surface methodology (RSM) and mass transfer modeling of heavy metals elimination using dolomite powder as an economical adsorbent. Case Studies in Chemical and Environmental Engineering, 7, 100329.

Khurshid, H., Mustafa, M.R.U., & Isa, M.H. (2022). Adsorption of chromium, copper, lead and mercury ions from aqueous solution using bio and nano adsorbents: a review of recent trends in the application of AC, BC, nZVI, and MXene. Environmental Research, 212, 113138.

Kun, C.C., Yang, L.P., & Chang, M.C. (2022). Adsorption of heavy metal ions by sodium chelating PAN fabrics. Results in Materials, 16, 100344.

Lagergren, S. (1898). Zur theorie der Sogenannten Adsorption Gelöster Stoffe. Kungliga Svenska Vetenskapsakademiens Handlingar, 24(4), 1-39.

Larous, S., & Meniai, A.H. (2012). Removal of copper (II) from aqueous solution by agricultural by-products-sawdust. Energy Procedia, 18, 915-923.

Lao, C., Zeledón, Z., Gamisans, X., & Solé, M. (2005). Sorption of Cd (II) and Pb (II) from aqueous solutions by a low-rank coal (leonardite). Separation and purification technology, 45(2), 79-85.

Li, Z., Lu, G., Du, D., & Zhao, D. (2024). Harnessing low-cost adsorbents for removal of heavy metals and metalloids in contaminated water: Progress in the past decade and future perspectives. Journal of Cleaner Production, 518, 145845.

Lindim, C., de Varennes, A., Torres, M.O., & Mota, A.M. (2001). Remediation of sandy soil artificially contaminated with cadmium using a polyacrylate polymer. Communications in Soil Science and Plant Analysis, 32(9-10), 1567-1574.

Liu, Z., Sang, J., Zhu, M., Feng, R., & Ding, X. (2024). Prediction and countermeasures of heavy metal copper pollution accident in the Three Gorges Reservoir Area. Journal of Hazardous Materials, 465, 133208.

Long, X., Zhang, R., Rong, R., Wu, P., Chen, S., Ao, J., An, L., Fu, Y., & Xie, H. (2023). Adsorption Characteristics of Heavy Metals Pb2+ and Zn2+ by Magnetic Biochar Obtained from Modified AMD Sludge. Toxics, 11(7), 590.

Mahmood, T., Saddique, M. T., Naeem, A., Westerhoff, P., Mustafa, S., & Alum, A. (2011). Comparison of Different Methods for the Point of Zero Charge Determination of NiO. Industrial & Engineering Chemistry, 50, 10017–10023.

Macena, M., Pereira, H., Cruz-Lopes, L., Grosche, L., & Esteves, B. (2025). Competitive adsorption of metal ions by lignocellulosic materials: A review of applications, mechanisms and influencing factors. Separations, 12(3), 70.

Meng, F., Yuan, G., Larson, S.L., Ballard, J.H., White, J.R., Arslan, Z., & Han, F.X. (2019). Kinetics and thermodynamics of uranium (VI) adsorption onto humic acid derived from leonardite. International Journal of Environmental Research and Public Health, 16(9), 1552.

Nelson D.W., & Sommers L.E. (1982). Total carbon, organic carbon, and organic matter. In A. L. Page et al. (Ed.), Methods of Soil Analysis. (Part 2). 2nd ed. (pp. 539–579). Agron. Monogr. 9. ASA and SSSA, Madison, WI.

Osman, H., Uğurlu, M., Vaizoğullar, A.İ., ... (2024). Statistical modeling and optimization of heavy metals (Pb and Cd) adsorption from aqueous solution by synthesis of Fe3O4/SiO2/PAM: isotherm, kinetics, and thermodynamic. Polymer Bulletin, 81, 14513–14545.

Paradelo, R., Cambier, P., Jara-Miranda, A., Jaulin, A., Doublet, J., & Houot, S. (2015). Mobility of Cu and Zn in Soil Amended with Composts at Different Degrees of Maturity. Waste and Biomass Valorization, 7, 513–522.

Pehlivan, E., Altun, T., & Parlayici, Ş. (2012). Modified barley straw as a potential biosorbent for removal of copper ions from aqueous solution. Food Chemistry, 135(4), 2229-2234.

Piri, M., Sepehr, E., Samadi, A., Farhadi, K., & Alizadeh, M. (2021). Application of diatomite for sorption of Pb, Cu, Cd and Zn from aqueous solutions: Kinetic, thermodynamic studies and application of response surface methodology (RSM). Water Environment Research, 93(7), 714–726.

Piri, M., & Sepehr, E. (2017). The feasibility of using of diatomite for removal of lead and cadmium from aqueous solutions by batch system. Iranian Journal of Soil and Water Research.

Renu, Agarwal, M., & Singh, K. (2023). Experimental study of competitive heavy metals removal from multimetal solution using wheat bran as a biomaterial: Response surface methodology. Environmental Progress & Sustainable Energy, 42(6), e14288.

Sanchez, A.G., Ayuso, E.A., & De Blas, O.J. (1999). Sorption of heavy metals from industrial waste water by low-cost mineral silicates. Clay Minerals, 34(3), 469–477.

Singanan, M., & Peters, E. (2013). Removal of toxic heavy metals from synthetic wastewater using a novel biocarbon technology. Journal of Environmental Chemical Engineering, 1(4), 884-890.

Terdputtakun, A., Arqueropanyo, O. A., Sooksamiti, P., Janhom, S., & Naksata, W. (2017). Adsorption isotherm models and error analysis for single and binary adsorption of Cd (II) and Zn (II) using leonardite as adsorbent. Environmental Earth Sciences, 76(22), 777.

Thomas, G. W. (1982). Exchangeable cations. pp 159-164. In: Page, A. L. et al. (Eds). Methods of Soil Analysis, ASA, SSSA, Madison, WI.

Tlili, A., Dridi, I., De Feudis, M., Vittori Antisari, L., & Jedidi, N. (2024). Boron characterization and distribution in particle-size fractions and humic substances in forest and agricultural Tunisian soils. Euro-Mediterranean Journal for Environmental Integration, 9, 1-14.

Veli, S., & Alyuz, B. (2007). Adsorption of copper and zinc from aqueous solutions by using natural clay. Journal of Hazardous Materials, 149(1), 226-233.

Wang, M., Zheng, X., Oba, B.T., Lin, Y., Shen, C., Huang, X., Yang, F., Xiao, Q., & Ding, Y. (2026). Innovations in nanomaterials for remediation of heavy metal−polluted soil: advances, mechanistic insights, and future prospects. Nano Materials Science, 8(1), 11-35.

Xu, J., Yang, L., Wang, Z., Dong, G., Huang, J., & Wang, Y. (2006). Toxicity of copper on rice growth and accumulation of copper in rice grain in copper contaminated soil. Chemosphere, 62(4), 602-607.

Xu, C., Liu, Q., Han, Y., Hu, S., & Xu, S. (2025). Efficient adsorption of Cu²⁺ using ZnCo bimetallic organic frameworks loaded cellulose-based modified aerogel: Adsorption behavior and mechanism. Environmental Research, 269, 120877.

Yang, X., Zhou, Y., Hu, J., Zheng, Q., Zhao, Y., Lv, G., & Liao, L. (2024). Clay minerals and clay-based materials for heavy metals pollution control. Science of The Total Environment, 954, 176193.

Zhang, J.W., Hai, N.D., Kholif, M.A., & Chao, H.P. (2025). Adsorption of heavy metals from water using teak-based carbon material through graft copolymerization. Carbon Resources Conversion, 8(4), 100332.