| تعداد نشریات | 127 |
| تعداد شمارهها | 7,119 |
| تعداد مقالات | 76,512 |
| تعداد مشاهده مقاله | 152,924,882 |
| تعداد دریافت فایل اصل مقاله | 115,070,626 |
سنتز و ارزیابی عملکرد نانو میله مولیبدن تری اکسید و نانوکامپوزیت مولیبدن تری اکسید-گرافن اکسید برای جذب آفتکش آبامکتین از محیطزیست | ||
| دانش گیاهپزشکی ایران | ||
| دوره 55، شماره 2، اسفند 1403، صفحه 311-330 اصل مقاله (1.73 M) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22059/ijpps.2025.390473.1007073 | ||
| نویسندگان | ||
| راضیه رضوی1؛ مسلم بسیج* 2؛ زینب نظری1؛ ساجده محمدی1؛ زهرا خادمی1؛ سلمان امیری3 | ||
| 1گروه شیمی ، دانشکده علوم ، دانشگاه جیرفت، جیرفت، ایران | ||
| 2گروه گیاهپزشکی، دانشکده کشاورزی، دانشگاه جیرفت، جیرفت، ایران | ||
| 3گروه گیاهپزشکی ، دانشکده کشاورزی ، دانشگاه جیرفت، جیرفت، ایران | ||
| چکیده | ||
| آفت کشهای کشاورزی بهعنوان آلایندههای محیط زیستی، تهدید جدی برای سلامت انسان و اکوسیستمهای طبیعی محسوب میشوند. در این پژوهش، نانومیلههای سوزنی شکل مولیبدن تریاکسید (MoO₃) به روش هیدروترمال و نانوکامپوزیت تری اکسید مولیبدن -گرافن اکسید (MoO₃@GO) بهصورت هتروژن سنتز شدند و کارایی آنها در حذف آفت کش آبامکتین مورد بررسی قرار گرفت. مشخصهیابی نانوذرات سنتز شده با استفاده از پراش پرتو ایکس (XRD)، میکروسکوپ الکترونی روبشی (SEM) و طیفسنجی مادون قرمز (FT-IR) انجام شد. نتایج نشان داد که میانگین اندازه نانومیلههای MoO₃ حدود 110 نانومتر است. مطالعات جذب نشان داد که هر دو جاذب از بازده جذب بالایی برخوردارند، با این حال نانوکامپوزیت MoO₃@GO با بازدهی 98% نسبت به نانومیلههای خالص MoO₃ (95%) عملکرد بهتری داشت. پارامترهای مؤثر در فرآیند جذب شامل غلظت اولیه آفتکش (5 پی پی ام) ، مقدار جاذب (3 میلیگرم)، زمان تماس (15 دقیقه) و pH اسیدی بهینهسازی شدند. مدل ایزوترم جذب از نوع لانگمویر بود که نشاندهنده جذب تک لایهای است. این مطالعه نشان داد که نانوکامپوزیت MoO₃@GO میتواند بهعنوان جاذب مؤثری برای حذف آلایندههای آلی از محیطهای آبی مورد استفاده قرار گیرد. | ||
| کلیدواژهها | ||
| جذب؛ آبامکتین؛ نانو میله؛ مولیبدن تری اکسید؛ ایزوترم جذب | ||
| مراجع | ||
|
REFERENCES Abbasi, A., Hamadanian, M., Gholami, T., Salavati-Niasari, M., & Sadri, N., (2018) Facile preparation of PbCrO4 and PbCrO4 /Ag nanostructure as an effective photocatalyst for degradation of organic contaminants, Separation and Purification Technolog, 5 (2), 571-580. https://doi.org/10.1016/j.seppur.2018.07.018. Bokhale N.B., Bomble, R.R. Dalbhanjan, D.D. Mahale, S.P. Hinge, B.S. Banerjee, A.V. Mohod, & Gogate, P.R., (2014), Sonocatalytic and sonophotocatalytic degradation of rhodamine 6G containing wastewaters, Ultrasonics Sonochemistry, 21, 1797-1804. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Bloomquist, J. R., Ion channels as targets for insecticides, Annual Review of Entomology. 41 (1996) 163–190. https://doi.org/10.1146/annurev.en.41.010196.001115. Campbell W.C., (2012), Ivermectin and abamectin, Springer Science & Business Media. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Campbell, W.C., Fisher, M.H., Stapley, E.O., Albers-Schönberg, G., & Jacob, T.A., (1983), Ivermectin: A potent new antiparasitic agent, Science (80-. ). 221, 823–828. https://doi.org/10.1126/science.6308762. Chen, Y., Fan, Y., Huang, Y., Liao, X., Wenfeng, X., & Zhang, T., (2024), A comprehensive review of toxicity of coal fly ash and its leachate in the ecosystem, Ecotoxicology and Environmental Safety, 269, 115905. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Chen, X., Qu, Z., Liu, Z., & Ren, G., (2022), Mechanism of oxidization of graphite to graphene oxide by the hummers method, ACS Omega 7, 23503–23510. https://doi.org/10.1021/acsomega.2c01963. Dionisio A.C., & Rath, S., (2016), Abamectin in soils: analytical methods, kinetics, sorption and dissipation, Chemosphere, 151, 17-29. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Ghalwa, A., Nasser, M., & Farhat N.B., (2015), Removal of abamectin pesticide by electrocoagulation Process using stainless steel and iron electrodes, Journal of Environmental Analytical Chemistry, 2:3 http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Ghafoori, S.A., Mowla, R., Jahani, M., Mehrvar, & P.K. Chan, (2015), Sonophotolytic degradation of synthetic pharmaceutical wastewater: Statistical experimental design and modeling, Journal of Environmental Management, 150, 128-137. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Hu, B., Wu, C., Zhang, Z., & Wang, L., (2014), Sonophotocatalytic degradation of trichloroacetic acid in aqueous solution, Ceramics International ,40, 7015-7021. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Joseph C.G., Puma, G.L., Bono, A., Taufiq-Yap, Y.H., & Krishnaiah, D., (2011), Operating parameters and synergistic effects of combining ultrasound and ultraviolet irradiation in the degradation of 2, 4, 6-trichlorophenol, Desalination, 276, 303-309. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Kralj, M.B. Franko, M., & Trebše, P., (2007), Photodegradation of organophosphorus insecticides-Investigations of products and their toxicity using gas chromatography–mass spectrometry and AChE-thermal lens spectrometric bioassay, Chemosphere, 67 99-107. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Khorasanizadeh, M.H., Monsef, R., Salavati-Niasari, M., Majdi, H.S., Al-Azzawi, W.K., & Hashim, F.S., (2023), Schiff-base ligand assisted synthesis of DyVO4/ AgBr nanocomposites, characterization, and investigation of photocatalytic activity over organic dye contaminants, Arabian Journal of Chemistry, 16, 105020. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Khojasteh, H., Salavati-Niasari, M., & Sangsefidi, F.S., (2018), Photocatalytic evaluation of RGO/TiO2NWs/Pd-Ag nanocomposite as an improved catalyst for efficient dye degradation, Journal of Alloys and Compounds, 746, 611-618. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Kumari, K., Singh, M., Tomar, N., Kumar, A., & Singh, P., (2023). Adsorption of pesticides using graphene oxide through computational and experimental approach. Journal of Molecular Structure. Vol. 1291, article id. 136043. Mokhtari, P., Ghaedi, M., Dashtian, K., Rahimi, M.R., & Purkait, M.K., (2016), Removal of methyl orange by copper sulfide nanoparticles loaded activated carbon: Kinetic and isotherm investigation, Journal of Molecular Liquids, 219, 299-305. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Mosleh S., Rahimi, M., Ghaedi, M., Dashtian, K., & Hajati, S., (2016), Photocatalytic degradation of binary mixture of toxic dyes by HKUST-1 MOF and HKUST-1-SBA-15 in a rotating packed bed reactor under blue LED illumination: central composite design optimization, RSC Advances ,6 , 17204-17214. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Mosleh S., Rahimi, M., Ghaedi, M., Dashtian, K., & Hajati, S., (2016), BiPO4/Bi2S3-HKUST-1-MOF as a novel blue light-driven photocatalyst for simultaneous degradation of toluidine blue and auramine-O dyes in a new rotating packed bed reactor: optimization and comparison to a conventional reactor, RSC Advances ,6, 63667-63680. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Meng X., Zhang, Z., & Li, X., (2015), Synergetic photoelectrocatalytic reactors for environmental remediation: A review, Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 24, 83-101. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Mohammed A.A., & Ali, D.K., (2023), Bentonite-layered double hydroxide composite as potential adsorbent for removal of abamectin pesticide from wastewater, Results in Surfaces and Interfaces, 10, 100099. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Matos, T.A.F., Dias, A.L.N., Reis, A.D.P., Silva, M.R.A., & Kondo, M.M., (2012) , Degradation of Abamectin Using the Photo-Fenton Process, International Journal of Chemical Engineering, 915724. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Soleiman, M., & Rahimi, M.R., (2016), Intensification of abamectin pesticide degradation using the combination of ultrasonic cavitation and visible-light driven photocatalytic process: synergistic effect and optimization study, Ultrasonics Sonochemistry, 21, 1797-1804, http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Nazé, P., (2023), Adiabatic processes like isothermal processes, Physical Review E, 107. https://doi.org/10.1103/PhysRevE.107.064114. McKellar, Q.A., & Benchaoui, H.A., (1996), Avermectins and milbemycins, Journal of Veterinary Pharmacology and Therapeutics, 19, 331–351. https://doi.org/10.1111/j.1365-2885.1996.tb00062.x. Rout, D. R., Jena,H.M., Baigenzhenov, O. R. & Bandegharaei, A. H., (2023), Graphene-based maerials for effective adsorption of organic and inorganic pollutants: A critical and comprehensive review. Science of the Total Environments, Volume 863, Article 160871 Nai-Qing, S., Wang, G., Li, Y., & Baia, S., (2020), Removal of abamectin and conventional pollutants in vertical flow constructed wetlands with Fe modified biochar, RSC Advances, 10, 44171. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Omura, S., (1998) Ivermectin, 25 years and still going strong, International Journal of Antimicrobial Agents, 31, 91–98. Sathishkumar, P., Mangalaraja, R.V., Rozas, O., Mansilla, H.D., Gracia-Pinilla, M., Anandan, S., Gracia-Pinilla, M.A., & Anandan, S., (2014) , Low frequency ultrasound (42 kHz) assisted degradation of Acid Blue 113 in the presence of visible light driven rare earth nanoclusters loaded TiO2 nanophotocatalysts, Ultrasonics Sonochemistry, 21 ,1675-1681. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Shehdeh, J., Khalaf, O., Obaid, A.A., Hammouti, B., Hadda, T.B., Jodeh, W., Haddad, M., & Warad, I., (2014), Adsorption and kinetics Study of abamectin and imidacloprid in greenhouse soil in Palestine, Journal of Materials and Environmental Science. 5 (2), 571-580. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Tadawatta, P., Kawashima, K., Sittiwanichai, S., Thienprasert, T., Mori, T., & Pongprayoon, P., (2025). Exploring the capabilities of nonosized graphene oxide as a pesticide nanosorbent stimulation studies. ACS Omega, 10(9) 8951-8959. Taghiyeva, N., Hasanova, U., Millet, M., Gardiennet, C., & Gakhramanova, Z., (2024). Synthesis and characterization of novel adsorbent based on functionalization of graphene with Schiff base and reduces schiff base for pesticide removal. Materials 17 (16), 4096. Vipin, K., Wang, X., & Lee, P.S., (2013) ,Synthesis of pyramidal and prismatic hexagonal MoO3 nanorods using thiourea, CrystEngComm, 15, 7663–7669. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Wang, S. H., Zeng, X. C., Ho, Q. W. & Zheng, Y. G., (2015) Degradation of abamectin by newly isolated Stenotrophomonas maltophilia ZJB-14120 and characterization of its abamectin-tolerance mechanism. Research in Biotechnology, 166(5):408-418. Wu, T.Y., Guo, N., Teh, C.Y., & Hay, J.X.W., (2012), Advances in ultrasound technology for environmental remediation, Springer Science & Business Media. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025 Wall, R., & Strong, L., (1987), Environmental consequences of treating cattle with the antiparasitic drug ivermectin, Nature 327, 418–421. https://doi.org/10.1038/327418a0. Xiong S.F., Yin, Z.L., Yuan, Z.F., Yan, W.B., Yang, W.Y., Liu, J.J., & Zhang, F., (2012), Dual-frequency (20/40 kHz) ultrasonic assisted photocatalysis for degradation of methylene blue effluent: synergistic effect and kinetic study, Ultrasonics Sonochemistry, 19, 756-761. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. Yuan-Shan, W., Zheng, X., Qi-Wei, H., & Zheng, Y., (2015), Degradation of abamectin by newly isolated Stenotrophomonas maltophilia ZJB-14120 and characterization of its abamectin-tolerance mechanism, Research in Microbiology, 166, 408-418. http://dx.doi.org/10.1016/j.ultsonch.2016.10.025. | ||
|
آمار تعداد مشاهده مقاله: 308 تعداد دریافت فایل اصل مقاله: 137 |
||