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برهمکنش اجزای مختلف کربن آلی با شکلهای مختلف آهن و آلومینیوم در خاکهای دارای خواص اندیک تیمار شده با اسید هیومیک | ||
تحقیقات آب و خاک ایران | ||
دوره 56، شماره 4، تیر 1404، صفحه 899-917 اصل مقاله (1.52 M) | ||
نوع مقاله: مقاله پژوهشی | ||
شناسه دیجیتال (DOI): 10.22059/ijswr.2025.385625.669840 | ||
نویسندگان | ||
محمد علی منجم1؛ احمد حیدری* 2 | ||
1گروه علوم و مهندسی خاک، دانشکده کشاورزی، دانشگا تهران، کرج، ایران | ||
2گروه علوم و مهندسی خاک، دانشکده کشاورزی، دانشگاه تهران، کرج، ایران | ||
چکیده | ||
کمپلکسهای آلی-معدنی که عمدتا حاصل برهمکنش اجزای کربن آلی با مواد معدنی خاک هستند، از مهمترین عوامل تاثیرگذار بر چرخه کربن و کارکردهای خاک میباشند. هدف این مطالعه بررسی نقش کانیهای آلوفانی و اشکال مختلف آهن و آلومینیم خاک، در تثبیت کربن آلی ورودی میباشد. اجزای کربن آلی و اشکال مختلف آهن و آلومینیوم قبل و بعد از تیمار دوازده نمونه خاک دارای خواص اندیک با اسید هیومیک به مدت شش ماه در شرایط آزمایشگاهی، اندازهگیری شدند. نتایج نشان نشان داد، تثبیت کربن آلی، با تشکیل کمپلکسهای آلی- معدنی، عمدتا توسط کانیهای با آرایشدامنهکوتاه (آلوفان) کنترل میشود. تشکیل کمپلکسهای سطحی بین عوامل پیوندی واقع در سطوح مواد معدنی و موادآلی، یکی از مهمترین فرایندهای تثبیت موادآلی در خاک است. کمپلکسهای آلومینیم و/یا آهن–هوموس دیگر عامل مهم در تثبیت موادآلی خاک میباشند. تثبیت و تشکیل کمپلکس با موادآلی، کانیهای با درجه تبلور پایین، آهن آمورف (Feo)، نبست به Alo آمورف مهمترین نقش را در تثبیت مواد آلی دارند. مقایسه میانگین (05/0p<) مقادیر اشکال سیلیس و آهن اگزالاتی (Feo، Sio)؛ پیروفسفاتی (Alp، Fep) و کل Fet حاکی از اختلاف معنیدار بین نمونههای تیمار و شاهد بود. افزودن اسید هیومیک با تشکیل کمپلکسهای آلی نامحلول با سطوح کانیها از یک طرف، و آلومینیم و آهنِ آزاد شده در خاک از طرف دیگر موجب تثبیت بیشتر کربن آلی در خاک شده است. تشکیل پلهای کاتیونی بین بار الکتریکی گروههای عاملی اسیدهیومیک با آلوفانها و تشکیل کمپلکسهای آلی- فلزی پایدار مانع استخراج آهن و آلومینیوم توسط اگزالات آمونیوم و یا پیروفسفات سدیم شد. | ||
کلیدواژهها | ||
کمپلکس آلی_ معدنی؛ هیومیک اسید؛ عناصر قابل استخراج (آلومینیم و آهن)؛ سدیم هیپوکلریت؛ اسید هیدروفلوئوریک | ||
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