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Organo-Metallic Palladium Complexes used for CO2 Storage and Environmental Remediation | ||
| Pollution | ||
| دوره 9، شماره 2، تیر 2023، صفحه 693-701 اصل مقاله (1.06 M) | ||
| نوع مقاله: Original Research Paper | ||
| شناسه دیجیتال (DOI): 10.22059/poll.2022.348855.1632 | ||
| نویسندگان | ||
| Zinah Nazih Mahmood1؛ Mahasin Alias1؛ Emad Yousif* 2؛ Shaymaa Baqer1؛ Mohammed Kadhom3؛ Dina Ahmed4؛ Ahmed Ahmed5؛ Amani Husain5؛ Muhammad Yusop6؛ Ali Jawad7 | ||
| 1Department of Chemistry, College of Science for Women, University of Baghdad, Baghdad, Iraq | ||
| 2Department of Chemistry, College of Science, Al-Nahrain University, Baghdad, Iraq | ||
| 3Department of Environmental Science, College of Energy and Environmental Science, Al-Karkh University of Science, Baghdad, Iraq | ||
| 4Department of Medical Instrumentation Engineering, Al-Mansour University College, Baghdad, Iraq | ||
| 5Polymer Research Unit, College of Science, Al-Mustansiriyah University, Baghdad, Iraq | ||
| 6School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, Bangi, Selangor, Malaysia | ||
| 7Faculty of Applied Sciences, Universiti Teknologi MARA, 40450, Shah Alam, Selangor, Malaysia | ||
| چکیده | ||
| Gas storage is an important branch of technology that has many economic and environmental aspects. This technique could save gas to the need time and contribute to solving the CO2 and global warming problems. In this work, the structure and physicochemical properties of the prepared palladium complex were characterized in the solid and solution states using spectroscopic techniques. These examination methods include ultraviolet-visible (UV-Vis), Fourier transform infrared (FTIR), metal and elemental analyses, and measurements of magnetic susceptibility and conductivity at room temperature. Also, findings on the surface morphology and surface area were provided via Field emission scanning electron microscopy (FESEM) and Brunauer–Emmett–Teller (BET) techniques, respectively. High-pressure adsorption measurements were investigated by storing carbon dioxide, and the results proved that such materials own remarkable gas adsorption properties that make them a good option for gas separation and storage. Gases uptake at 323 K for the complexes leads to the highest CO2 uptake. The prepared material could pave the road for further exploitation of similar materials. | ||
| کلیدواژهها | ||
| sodium fusidate؛ transition metal؛ gas separation؛ gas storage؛ gases uptake | ||
| مراجع | ||
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