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Haddadnezhad, MohammadNavid, Babaei, Alireza, Molaei, Mohammad Jafar, Ataie, Abolghasem. (1399). Synthesis and characterization of lanthanum nickelate nanoparticles with Rudllesden-Popper crystal structure for cathode materials of solid oxide fuel cells. , 53(2), 98-109. doi: 10.22059/jufgnsm.2020.02.01
MohammadNavid Haddadnezhad; Alireza Babaei; Mohammad Jafar Molaei; Abolghasem Ataie. "Synthesis and characterization of lanthanum nickelate nanoparticles with Rudllesden-Popper crystal structure for cathode materials of solid oxide fuel cells". , 53, 2, 1399, 98-109. doi: 10.22059/jufgnsm.2020.02.01
Haddadnezhad, MohammadNavid, Babaei, Alireza, Molaei, Mohammad Jafar, Ataie, Abolghasem. (1399). 'Synthesis and characterization of lanthanum nickelate nanoparticles with Rudllesden-Popper crystal structure for cathode materials of solid oxide fuel cells', , 53(2), pp. 98-109. doi: 10.22059/jufgnsm.2020.02.01
Haddadnezhad, MohammadNavid, Babaei, Alireza, Molaei, Mohammad Jafar, Ataie, Abolghasem. Synthesis and characterization of lanthanum nickelate nanoparticles with Rudllesden-Popper crystal structure for cathode materials of solid oxide fuel cells. , 1399; 53(2): 98-109. doi: 10.22059/jufgnsm.2020.02.01

Synthesis and characterization of lanthanum nickelate nanoparticles with Rudllesden-Popper crystal structure for cathode materials of solid oxide fuel cells

Journal of Ultrafine Grained and Nanostructured Materials
دوره 53، شماره 2، اسفند 2020، صفحه 98-109    اصل مقاله (5.76 M)
نوع مقاله: Research Paper
شناسه دیجیتال (DOI): 10.22059/jufgnsm.2020.02.01
نویسندگان
MohammadNavid Haddadnezhad1؛ Alireza Babaei1؛ Mohammad Jafar Molaei* 2؛ Abolghasem Ataie1
1School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran.
2Faculty of Chemical and Materials Engineering, Shahrood University of Technology, Shahrood, Iran.
چکیده
Lanthanum nickelate with the chemical formula of La2NiO4+δ has attracted research interests during recent years, due to its hA high oxygen ion diffusivity for application as cathode material in solid oxide fuel cells (SOFCs). In this research, lanthanum nickelate with Ruddlesden–Popper (RP) crystal structure was synthesized via the co-precipitation method. The effects of OH-/NO3- molar ratio, La3+/Ni2+ molar ratio, co-precipitation temperature, and calcination temperature on the phase composition, thermal behavior, morphology, and electrochemical properties of the synthesized samples were investigated. Analysis of the X-ray diffractometry (XRD) patterns revealed that the optimum OH-/NO3- and La3+/Ni2+ molar ratios in the co-precipitation stage are 1.25 and 1.7, respectively. The formation of RP lanthanum nickelate is promoted by calcination of the co-precipitated powder at 1000 °C, while the calcination at lower temperatures may lead to the formation of perovskite (P) lanthanum nickelate. Scanning electron microscopy (SEM) studies showed that the mean particle size decreases from 428 to 332 nm by increasing the OH-/NO3- molar ratio from 1 to 1.5 while it increases from 67 to 183 nm by increasing the calcination temperature from 900 to 1000 °C. Simultaneous differential thermal analysis (DTA/TG) showed that the single RP lanthanum nickelate phase starts to form at 920 °C and fully formed at 960 °C. The electrochemical impedance spectroscopy data indicated that the cell with the electrode sintered at 1050 °C has the lowest polarization resistance. The polarization resistance reached 1 Ω cm2 at the testing temperature of 800 °C, for the electrode sintered at 1050 °C. Impedance curves of the electrode were fitted and simulated with two semicircles at high and low frequencies. The activation energy of 1.14 eV was calculated for the electrode polarization resistance of the lanthanum nickelate electrode.
کلیدواژه‌ها
Lanthanum nickelate؛ co-precipitation؛ SOFCs؛ Rudllesden-popper
مراجع

1. Bu Y, Joo S, Zhang Y, Wang Y, Meng D, Ge X, et al. A highly efficient composite cathode for proton-conducting solid oxide fuel cells. Journal of Power Sources. 2020;451:227812.

2. Basbus J, Arce M, Troiani H, Su Q, Wang H, Caneiro A, et al. Study of BaCe0.4Zr0.4Y0.2O3-δ/BaCe0.8Pr0.2O3-δ (BCZY/BCP) bilayer membrane for Protonic Conductor Solid Oxide Fuel Cells (PC-SOFC). International Journal of Hydrogen Energy. 2020;45(8):5481-90.

3. Pei K, Zhou Y, Xu K, He Z, Chen Y, Zhang W, et al. Enhanced Cr-tolerance of an SOFC cathode by an efficient electro-catalyst coating. Nano Energy. 2020;72:104704.

4. Baba S, Ohguri N, Suzuki Y, Murakami K. Evaluation of a variable flow ejector for anode gas circulation in a 50-kW class SOFC. International Journal of Hydrogen Energy. 2020;45(19):11297-308.

5. Abdalla AM, Hossain S, Azad AT, Petra PMI, Begum F, Eriksson SG, et al. Nanomaterials for solid oxide fuel cells: A review. Renewable and Sustainable Energy Reviews. 2018;82:353-68.

6. He T, Zhou Q, Jin F. Cathodes for Solid Oxide Fuel Cell. Solid Oxide Fuel Cells: Wiley; 2020. p. 79-112.

7. Laguna-Bercero MA, Monzón H, Larrea A, Orera VM. Improved stability of reversible solid oxide cells with a nickelate-based oxygen electrode. Journal of Materials Chemistry A. 2016;4(4):1446-53.

8. Kolchugin AА, Pikalova EY, Bogdanovich NM, Bronin DI, Pikalov SM, Plaksin SV, et al. Structural, electrical and electrochemical properties of calcium-doped lanthanum nickelate. Solid State Ionics. 2016;288:48-53.

9. Burriel M, Téllez H, Chater RJ, Castaing R, Veber P, Zaghrioui M, et al. Influence of Crystal Orientation and Annealing on the Oxygen Diffusion and Surface Exchange of La2NiO4+δ. The Journal of Physical Chemistry C. 2016;120(32):17927-38.

10. Antonova EP, Khodimchuk AV, Tropin ES, Porotnikova NM, Farlenkov AS, Vlasov MI, et al. Influence of modifying additives on electrochemical performance of La2NiO4+δ - based oxygen electrodes. Solid State Ionics. 2020;346:115215.

11. Gong Y, Wang R, Banner J, Basu SN, Pal UB, Gopalan S. Improved Tolerance of Lanthanum Nickelate (La2NiO4+δ) Cathodes to Chromium Poisoning Under Current Load in Solid Oxide Fuel Cells. JOM. 2019;71(11):3848-58.

12. Khamidy NI, Laurencin J, Ferreira Sanchez D, Monaco F, Charlot F, Djurado E. Durability of nanostructured LaPrNiO4+δ electrode for solid oxide cells: Electrochemical, microstructural, and structural investigation. Journal of Power Sources. 2020;450:227724.

13. Morales-Zapata MA, Larrea A, Laguna-Bercero MA. Reversible operation performance of microtubular solid oxide cells with a nickelate-based oxygen electrode. International Journal of Hydrogen Energy. 2020;45(8):5535-42.

14. Vibhu V, Vinke IC, Eichel R-A, Bassat J-M, de Haart LGJ. Cobalt Substituted Lanthanide Nickelates (Ln2Ni1-xCoxO4+δ, Ln = La, Pr; x=0, 0.1, 0.2) as High Performance Oxygen Electrodes for Solid Oxide Cells. ECS Transactions. 2019;91(1):1327-39.

15. Sakai M, Wang C, Okiba T, Soga H, Hashimoto T. Evaluation of stability of Pr2−xNdxNiO4+δ by thermogravimetry under various oxygen partial pressures. Journal of Thermal Analysis and Calorimetry. 2019;142(1):139-47.

16. Sadykov VA, Pikalova EY, Kolchugin AA, Fetisov AV, Sadovskaya EM, Filonova EA, et al. Transport properties of Ca-doped Ln2NiO4 for intermediate temperature solid oxide fuel cells cathodes and catalytic membranes for hydrogen production. International Journal of Hydrogen Energy. 2020;45(25):13625-42.

17. Zhao K, Xu Q, Huang D-P, Chen M, Kim B-H. Microstructure and electrochemical properties of porous La2NiO4+δ electrodes spin-coated on Ce0.8Sm0.2O1.9 electrolyte. Ionics. 2011;18(1-2):75-83.

18. Kim D, Lee KT. Effect of lanthanide (Ln=La, Nd, and Pr) doping on electrochemical performance of Ln2NiO4+δ−YSZ composite cathodes for solid oxide fuel cells. Ceramics International. 2021;47(2):2493-8.

19. Benamira M, Ringuedé A, Cassir M, Horwat D, Lenormand P, Ansart F, et al. Enhancing oxygen reduction reaction of YSZ/La2NiO4+δ using an ultrathin La2NiO4+δ interfacial layer. Journal of Alloys and Compounds. 2018;746:413-20.

20. Wu X, Gu C, Cao J, Miao L, Fu C, Liu W. Investigations on electrochemical performance of La2NiO4+δ cathode material doped at A site for solid oxide fuel cells. Materials Research Express. 2020;7(6):065507.

21. Yoo Y-S, Choi M, Hwang J-H, Im H-N, Singh B, Song S-J. La2NiO4+δ as oxygen electrode in reversible solid oxide cells. Ceramics International. 2015;41(5):6448-54.

22. Chroneos A, Parfitt D, Kilner JA, Grimes RW. Anisotropic oxygen diffusion in tetragonal La2NiO4+δ: molecular dynamics calculations. J Mater Chem. 2010;20(2):266-70.

23. Maas K, Villepreux E, Cooper D, Salas‐Colera E, Rubio‐Zuazo J, Castro GR, et al. Tuning Memristivity by Varying the Oxygen Content in a Mixed Ionic–Electronic Conductor. Advanced Functional Materials. 2020;30(17):1909942.

24. Baeumer C, Schmitz C, Ramadan AHH, Du H, Skaja K, Feyer V, et al. Spectromicroscopic insights for rational design of redox-based memristive devices. Nature communications. 2015;6:8610-.

25. Sadykov, V.A., Pikalova, E.Y., Kolchugin, A.A., Fetisov, A.V., Sadovskaya, E.M., Filonova, E.A., Eremeev, N.F., Goncharov, V.B., Krasnov, A.V., Skriabin, P.I. and Shmakov, A.N., Transport properties of Ca-doped Ln2NiO4 for intermediate temperature solid oxide fuel cells cathodes and catalytic membranes for hydrogen production. International Journal of Hydrogen Energy, 2018.

26. Gilev AR, Kiselev EA, Cherepanov VA. Bulk Oxygen Diffusion and Surface Exchange Limitations in La2−xSrxNi1-yFeyO4+δ. KnE Materials Science. 2018;4(2):24.

27. Garali M, Kahlaoui M, Mohammed B, Mater A, Azouz Cb, Chefi C. Synthesis, characterization and electrochemical properties of La2-xEuxNiO4+δ Ruddlesden-Popper-type layered nickelates as cathode materials for SOFC applications. International Journal of Hydrogen Energy. 2019;44(21):11020-32.

28. Usenka A, Pankov V, Vibhu V, Flura A, Grenier J-C, Bassat J-M. Temperature Programmed Oxygen Desorption and Sorption Processes on Pr2-XLaxNiO4+δ Nickelates. ECS Transactions. 2019;91(1):1341-53.

29. Wang C, Soga H, Yugi T, SAKAI M, Okiba T, Hashimoto T. Variation in crystal structure of Ln2Ni1− xCuxO4+ δ (Ln: La, Pr, Nd, Sm, Eu, and their solid solution) based on type of Ln: Relationship between crystal structure and tolerance factor. Journal of the Ceramic Society of Japan. 2019 Oct 1;127(10):678-87.

30. Antonova EP, Stroeva AY, Tropin ES. Electrode performance of La2NiO4+δ cathodes in contact with La0.9Sr0.1ScO3−δ proton-conducting oxide. Journal of Solid State Electrochemistry. 2020;24(7):1447-51.

31. Galal A, Atta NF, Hefnawy MA. Lanthanum nickel oxide nano-perovskite decorated carbon nanotubes/poly(aniline) composite for effective electrochemical oxidation of urea. Journal of Electroanalytical Chemistry. 2020;862:114009.

32. Antonova EP, Khodimchuk AV, Usov GR, Tropin ES, Farlenkov AS, Khrustov AV, et al. EIS analysis of electrode kinetics for La2NiO4 + δ cathode in contact with Ce0.8Sm0.2O1.9 electrolyte: from DRT analysis to physical model of the electrochemical process. Journal of Solid State Electrochemistry. 2019;23(4):1279-87.

33. Shen S, Williamson M, Cao G, Zhou J, Tsoi M. Resistive switching in tunnel junctions with a single-crystal La2NiO4 electrode. Journal of Physics D: Applied Physics. 2019;53(7):075302.

34. Wei M, Che W, Li H, Wang Z, Yan F, Liu Y, et al. Ruddlesden-Popper type La2NiO4+δ oxide coated by Ag nanoparticles as an outstanding anion intercalation cathode for hybrid supercapacitors. Applied Surface Science. 2019;484:551-9.

35. Hinterding R, Zhao Z, Zhang C, Feldhoff A. Anisotropic growth of La2NiO4+: Influential pre-treatment in molten-flux synthesis. Journal of Crystal Growth. 2019;523:125135.

36. Bouyer F, Sanson N, Destarac M, Gérardin C. Hydrophilic block copolymer-directed growth of lanthanum hydroxide nanoparticles. New Journal of Chemistry. 2006;30(3):399.

37. Praveena K, Sadhana K, Srinath S, Murthy SR. Effect of pH on structural and magnetic properties of nanocrystalline Y3Fe5O12 by aqueous co-precipitation method. Materials Research Innovations. 2013;18(1):69-75.

38. Briois P, Perry F, Billard A. Structural and electrical characterisation of lanthanum nickelate reactively sputter-deposited thin films. Thin Solid Films. 2008;516(10):3282-6.

39. Fontaine M-L, Laberty-Robert C, Barnabé A, Ansart F, Tailhades P. Synthesis of La2−xNiO4+δ oxides by polymeric route: non-stoichoimetry control. Ceramics International. 2004;30(8):2087-98.

40. Wu J, Pramana SS, Skinner SJ, Kilner JA, Horsfield AP. Why Ni is absent from the surface of La2NiO4+δ? Journal of Materials Chemistry A. 2015;3(47):23760-7.

41. Egger A, Schrödl N, Gspan C, Sitte W. La2NiO4+δ as electrode material for solid oxide fuel cells and electrolyzer cells. Solid State Ionics. 2017;299:18-25.

42. Jeong C, Lee J-H, Park M, Hong J, Kim H, Son J-W, et al. Design and processing parameters of La2NiO4+δ-based cathode for anode-supported planar solid oxide fuel cells (SOFCs). Journal of Power Sources. 2015;297:370-8.

43. Ferkhi M, Yahia HA. Electrochemical and morphological characterizations of La 2⿿x NiO 4±d (x = 0.01, 0.02, 0.03 and 0.05) as new cathodes materials for IT-SOFC. Materials Research Bulletin. 2016;83:268-74.

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