سامانه پشتیبانی خدمات اطلاعات

  اخبار و اعلانات

 آمار

تعداد نشریات161
تعداد شماره‌ها6,573
تعداد مقالات71,036
تعداد مشاهده مقاله125,508,798
تعداد دریافت فایل اصل مقاله98,772,121
Masteri-Farahani, M., Rahimpour, R.. (1395). New Hybrid Nanomaterial Derived from Immobilization of 4-Formyl Benzo-9-Crown-3 Ether onto the Mesopores of MCM-41. , 27(3), 223-230.
M. Masteri-Farahani; R. Rahimpour. "New Hybrid Nanomaterial Derived from Immobilization of 4-Formyl Benzo-9-Crown-3 Ether onto the Mesopores of MCM-41". , 27, 3, 1395, 223-230.
Masteri-Farahani, M., Rahimpour, R.. (1395). 'New Hybrid Nanomaterial Derived from Immobilization of 4-Formyl Benzo-9-Crown-3 Ether onto the Mesopores of MCM-41', , 27(3), pp. 223-230.
Masteri-Farahani, M., Rahimpour, R.. New Hybrid Nanomaterial Derived from Immobilization of 4-Formyl Benzo-9-Crown-3 Ether onto the Mesopores of MCM-41. , 1395; 27(3): 223-230.

New Hybrid Nanomaterial Derived from Immobilization of 4-Formyl Benzo-9-Crown-3 Ether onto the Mesopores of MCM-41

Journal of Sciences, Islamic Republic of Iran
مقاله 3، دوره 27، شماره 3، مهر 2016، صفحه 223-230    اصل مقاله (2.37 M)
نوع مقاله: Final File
نویسندگان
M. Masteri-Farahani* 1؛ R. Rahimpour2
11Faculty of Chemistry, Kharazmi University, Tehran, Islamic Republic of Iran
22Faculty of Chemistry, Islamic Azad University, Ardabil branch, Ardabil, Islamic Republic of Iran
چکیده
In this work, we report a new hybrid nanomaterial based on the immobilization of 4-formyl benzo-9-crown-3 ether (FB9C3) onto the mesopores of MCM-41. First, the mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl triethoxysilane to give aminopropyl modified MCM-41 (AmpMCM-41). Reaction of this material with FB9C3 afforded the B9C3-AmpMCM-41 hybrid nanomaterial. The prepared B9C3-AmpMCM-41 was characterized with different physicochemical methods such as Fourier transform infrared spectroscopy, X-ray diffraction  (XRD), scanning and transmission electron microscopy, thermogravimetric analysis (TGA-DTA), and BET nitrogen adsorption-desorption analysis. The XRD analysis revealed that textural properties of the support were preserved during the immobilization process. However, nitrogen adsorption-desorption analysis showed sequential reduction in surface area, pore volume, and pore size during the grafting experiments. Elemental analysis showed the presence of 0.11 mmol FB9C3 per gram of the hybrid nanomaterial. 
کلیدواژه‌ها
Mesoporous؛ MCM-41؛ Hybrid nanomaterial؛ Benzo-9-crown-3 ether؛ immobilization
آمار
تعداد مشاهده مقاله: 962
تعداد دریافت فایل اصل مقاله: 1,149





سامانه مدیریت نشریات علمی. قدرت گرفته از سیناوب